Results 41 to 50 of about 1,764 (168)

Separation of sterols by vapor-programmed thin-layer chromatography

open access: yesJournal of Lipid Research, 1970
By vapor-programmed thin-layer chromatography on silica gel, it was possible to separate cholestanol from cholesterol and stigmastanol from β-sitosterol. The method was applied for the analysis of β-sitosterol-3-14C.
W.H.J.M. Wientjens   +2 more
doaj   +1 more source

Case Report: Early Treatment With Chenodeoxycholic Acid in Cerebrotendinous Xanthomatosis Presenting as Neonatal Cholestasis

open access: yesFrontiers in Pediatrics, 2020
Background: Cerebrotendinous xanthomatosis (CTX) is an inborn disorder of bile acid synthesis which causes progressive accumulation of toxic metabolites in various organs, particularly in brain and tendons.
Irene Degrassi   +7 more
doaj   +1 more source

7α-Hydroxylation of cholestanol by rat liver microsomes

open access: yesJournal of Lipid Research, 1968
In a study of the mechanism whereby 5α-bile acids are formed from cholestanol, the 7α-hydroxylation of cholestanol was investigated in rat liver preparations in vitro.
Sarah Shefer   +2 more
doaj   +1 more source

Fecal Steroids as Tracers of Human Population and Waste Management Practices at the Ancient Maya City of Ucanal, Guatemala

open access: yesArchaeometry, Volume 68, Issue 4, Page 646-658, August 2026.
ABSTRACT Geochemical data compiled from dried sediments from three water reservoirs at the ancient Maya city of Ucanal, Petén, Guatemala, reveal low to undetectable fecal biomarker concentrations. These low concentrations may be the result of the aerobic decay of sterols combined with well‐managed waste disposal practices.
Jean D. Tremblay   +3 more
wiley   +1 more source

Iminodirhodium‐ and Iminocopper‐Catalyzed CH Activation: Chemoselective Oxidation of Alcohols and Aldehydes via Intermolecular Hydride Abstraction

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 25, 4 July 2026.
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu   +2 more
wiley   +1 more source

Chlorine‐Free Synthesis of P‐Esters: Microwave‐Assisted Direct Esterification of Phosphinic, Phosphonic, as Well as Phosphoric Acid Derivatives

open access: yesChemistry–Methods, Volume 6, Issue 7, July 2026.
The esterification of phosphinic, phosphonic, and phosphoric acids is not possible due the high enthalpy of activation. However, the barrier may be overcome under MW irradiation to give phosphinates, phosphonates, and alkoxyphosphoric acids, respectively. In the latter cases, the remaining P(O)OH group was esterified by alkylation.
György Keglevich
wiley   +1 more source

Differences in hepatic levels of intermediates in bile acid biosynthesis between Cyp27−/− mice and CTX

open access: yesJournal of Lipid Research, 2001
Cerebrotendinous xanthomatosis (CTX) is a rare, recessively inherited lipid storage disease characterized by a markedly reduced production of chenodeoxycholic acid and an increased formation of 25-hydroxylated bile alcohols and cholestanol. Patients with
Akira Honda   +9 more
doaj   +1 more source

Synthesis of conjugated cholesterol and cholestanols.

open access: yesChemical and Pharmaceutical Bulletin, 1979
The glucuronides, sulfates, glucosides and N-acetylglucosaminides of cholesterol and epimeric 5α-cholestan-3-ols have been synthesized. The formation of a β-glucoside linkage was readily achieved by means of the Koenigs-Knorr reaction with the corresponding α-acetohalosugar, employing cadmium carbonate as a catalyst.
GOTO, JUNICHI   +2 more
openaire   +1 more source

Serum plant sterols and biliary cholesterol secretion in humans

open access: yesJournal of Lipid Research, 2002
Ratios of cholestanol, campesterol, and sitosterol to cholesterol in serum are known to reflect cholesterol absorption efficiency. Here, a possible link between these ratios and biliary secretion rates of cholesterol was investigated.
Bernhard Lindenthal   +5 more
doaj   +1 more source

Phytochemicals in Asthma Management: Mechanism, Translational Gap and Clinical Integration

open access: yesPhytochemicals in Food and Medicine, Volume 1, Issue 2, June 2026.
The phytochemicals including flavonoids, alkaloids, terpenoids, and saponins modulate inflammatory, oxidative, and immune pathways in asthma. It highlights their mechanisms of action, translational challenges, advanced formulation strategies, and emerging clinical potential as adjunct therapies for precision‐based asthma management.
Pulak Majumder, Trisita Majumder
wiley   +1 more source

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