Results 181 to 190 of about 26,716 (284)

Simple s-block metal hydrides for selective hydrogenation of quinoline compounds. [PDF]

Chem Sci
Zhang S, Wen H, Wang Q, Cai Y, Li Z, Liu L, Chang X, Guo J, Chen P.   +8 more
europepmc   +1 more source

Synthesis of Sulfur Heterocycles by Palladium‐Catalyzed Cyclization

European Journal of Organic Chemistry, EarlyView.
In spite of the well‐known palladium thiophilicity, sulfur‐containing acyclic substrates may efficiently undergo several different kinds of palladium‐catalyzed cyclization processes leading to highly important sulfur heterocycles in one synthetic step. Advances in this challenging and stimulating field of research are presented in this review.
Bartolo Gabriele
wiley   +1 more source

Crystal Structure Investigations of LaNi₂H_<i>x</i> (<i>x</i> = 0 and 3.08 with Metal Atoms in AlB₂ Units) and LaNiH_1.01. [PDF]

Inorg Chem
Sato T, Utsumi R, Nakahira Y, Saitoh H, Honda T, Orimo SI.   +5 more
europepmc   +1 more source

Transfer Hydrogenation of Organic Azides to Amines by Ammonia Borane Complex Under Mild Conditions Catalyzed by Reusable Au Nanoparticles

European Journal of Organic Chemistry, EarlyView.
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda, Dimitra Malliotaki, Ioannis Zachilas, Andreas‐Drakos Kokkinos, Orestis Agathocleous, Manolis Stratakis   +5 more
wiley   +1 more source

Ab initio analysis of the structural, hydrogen storage, mechanical, electronic, and optical characteristics of Cs₂XAlH₆ (X = K, Na, Rb) double perovskite hydrides. [PDF]

Sci Rep
Al-Qawasmeh A, Abu-Rajouh S, Al-Mahmoud A, Al-Khaldi H, Obeidat A.   +4 more
europepmc   +1 more source

Enzymatic Synthesis of Demethylated Sesquiterpenes From 14‐nor‐Farnesyl Pyrophosphate

European Journal of Organic Chemistry, EarlyView.
The substrate analog 14‐nor‐FPP was synthesised and enzymatically converted with 10 bacterial and fungal sesquiterpene synthases, resulting in the isolation of 12 demethylated sesquiterpenes in yields up to 17%. In most cases the demethyl analogs of the FPP‐derived natural products were obtained, but also different products showing modified ...
Kizerbo A. Taizoumbe, Jeroen S. Dickschat   +1 more
wiley   +1 more source

An approach towards next-generation hydrogen storage: a DFT study on A₂LiTiH₆ (A = K, Ca) perovskite hydrides. [PDF]

RSC Adv
Ullah MA, Kaleem M, Nasir A, Sarfraz Z, Asif Iqbal MM, Rizwan M, Riaz KN, Tanzeel M.   +7 more
europepmc   +1 more source

Silyl Rearrangements in Gold‐Catalyzed Transformations

European Journal of Organic Chemistry, EarlyView.
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez, Luis A. López   +1 more
wiley   +1 more source

Structural and reactivity investigations using organo-copper(i) and zinc(ii) complexes with hydrogen and carbon dioxide. [PDF]

Chem Sci
Cowie BE, Phanopoulos A, Shaffer MSP, Williams CK.   +3 more
europepmc   +1 more source

A Sustainable Borrowing Hydrogen Strategy in Natural Deep Eutectic Solvents for the N‐Alkylation of Amines From Alcohols

European Journal of Organic Chemistry, EarlyView.
A sustainable, ligand‐free Pd‐catalyzed borrowing hydrogen protocol in a biodegradable hydrophobic natural deep eutectic solvent (NADES) (thymol/DL‐menthol) enables the N‐alkylation of primary amines with benzylic alcohols under mild, aerobic conditions, allowing efficient reuse of both catalyst and solvent for seven consecutive cycles. The hydrophobic
Maryam Saeb, Maristella Simone, Luciana Cicco, Paola Vitale, Filippo Maria Perna, Vito Capriati   +5 more
wiley   +1 more source