Results 161 to 170 of about 6,959 (207)

Nitroxide‐Mediated Polymerization Synthesis of Geminal Bisphosphonate‐Functionalized (Co)polymers and Their Affinity to Hydroxyapatite Surface

Journal of Polymer Science, EarlyView.
A novel styrenic monomer bearing gem‐bisphosphonate groups is synthesized in a single step. The nitroxide‐mediated (co)polymerization of this monomer proceeds in a well‐controlled manner, yielding bisphosphonate‐functionalized (co)polymers with low dispersity.
Hien The Ho, Nam Hoai Nguyen, Marion Rollet, Didier Gigmes, Trang N. T. Phan   +4 more
wiley   +1 more source

The X‐Ray Crystal Structure of BorF, the Flavin Reductase Subunit of a Two‐Component Flavin‐Dependent Tryptophan Halogenase

Proteins: Structure, Function, and Bioinformatics, EarlyView.
ABSTRACT BorF is a short‐chain flavin reductase from a desert soil bacterium that uses NADH to reduce FAD to FADH2, which is used by the tryptophan‐6‐halogenase BorH to chlorinate tryptophan in the biosynthetic pathway of borregomycin A. The X‐ray crystal structure of BorF bound to FAD was solved to 2.37 Å by molecular replacement.
Zheng Ma, Emily W. Rady, Aravinda J. de Silva, John J. Bellizzi III   +3 more
wiley   +1 more source

The path to room-temperature superconductivity: A programmatic approach. [PDF]

Proc Natl Acad Sci U S A
Prasankumar RP, Julian M, Hutcheon M, Heil C, Deng L, Basov D, Chu CW, Comin R, Kim P, Meredig B, Pickard C, E Pickett W, Strobel T, Wolf S, Zurek E, Myhrvold N.   +15 more
europepmc   +1 more source

Exploring the Fragmentation of Sodiated Species Involving Covalent‐Bond Cleavages for Metabolite Characterization

Rapid Communications in Mass Spectrometry, EarlyView.
ABSTRACT Rationale Electrospray (ESI), the most popular desorption/ionization technique used in mass spectrometry‐based metabolomics, generates both protonated and deprotonated molecules, as well as adduct ions, sodium being the most frequent monoatomic cation entering their composition.
Annelaure Damont, Ekaterina Darii, Chenqin Cao, Anaïs Legrand, Alain Perret, Sylvain Dechaumet, Amina S. Woods, Christophe Junot, Jean‐Claude Tabet, François Fenaille   +9 more
wiley   +1 more source

An approach towards next-generation hydrogen storage: a DFT study on A₂LiTiH₆ (A = K, Ca) perovskite hydrides. [PDF]

RSC Adv
Ullah MA, Kaleem M, Nasir A, Sarfraz Z, Asif Iqbal MM, Rizwan M, Riaz KN, Tanzeel M.   +7 more
europepmc   +1 more source

Potassium‐Doped Borophane Nanosheets: A Multifunctional Platform for Reversible Hydrogen Storage and Metal‐Free Hydrogen Transfer

Small, EarlyView.
Borophane in dual roles: as a reductant in the conversion of levulinic acid to γ‐valerolactone and as a reversible hydrogen reservoir through partial rehydrogenation. ABSTRACT 2D borophene has long been proposed as a promising hydrogen storage material, but experimental demonstrations remain limited to boron hydride sheets derived from MgB2.
Rajamohanan Sobhana Anju, Pankaj Kumar, Dhanaji R. Naikwadi, Bettina Baumgartner, Savi Chaudhary, Atul Bansode, Merel C. Konings, Freek Ariese, Erdni D. Batyrev, Prasad Gonugunta, Vimal Chandra Srivastava, Ramaswamy Murugavel, N. Raveendran Shiju   +12 more
wiley   +1 more source

From CO₂ to C₁ Liquid Fuels: Molecular Electrochemical Production of Formic Acid and Methanol. [PDF]

Angew Chem Int Ed Engl
Karapapa P, Mondal S, Zeglio E, Das B.
europepmc   +1 more source

Sequential Optimization of Multivariate Metal–Organic Framework Based Biocatalysis

Small, EarlyView.
A sequential Latin hypercube sampling–coupled Bayesian optimization (LHS‐BO) workflow integrates multivariate zirconium‐based metal–organic framework based biocomposite (E‐MOF) design with enzyme biocascade reaction optimization. The optimized E‐MOFs stabilize glucose oxidase and horseradish peroxidase in bioactive conformation, exhibiting high ...
Weibin Liang, Sisi Zheng, Ross Andrew Shalliker, Christian Doonan, Feng Li   +4 more
wiley   +1 more source

Synergistic C-H bond activation across molybdenum-iridium multiply bonded complexes: a cascade of transformations. [PDF]

Chem Sci
Dubrawski Z, Del Rosal I, Jeanneau E, Maron L, Thieuleux C, Camp C.   +5 more
europepmc   +1 more source

Going Deep into the Surface Chemistry of Carbon Dots: Influence of Functional Groups on the Redox Abilities

Small, EarlyView.
The chemical structure of Carbon Dots (CDs) is still a mystery despite years of study. Herein, we show how CDs with a higher density of surface‐accessible amines display enhanced (photo)redox performance. Electrochemical and thermodynamic analyses confirmed the feasibility of electron transfer, while mechanistic investigations revealed that the ...
Laura Morbiato, Maria Sbacchi, Jacopo Dosso, Paolo Pengo, Pierangelo Gobbo, Giacomo Filippini, Maurizio Prato   +6 more
wiley   +1 more source