Reverse bias stability remains a critical challenge for inverted perovskite solar cells (PSCs). While self-assembled monolayers (SAMs) boost efficiency, their low breakdown voltages limit device reliability.
Chaoyue Zhao +12 more
doaj +1 more source
Antiferromagnetic spin-coupling between MnII and amminium radical cation ligands: models for coordination polymer magnets [PDF]
One and two electron oxidation of the manganese(II) complex [L2Mn(hfac)2] {L = 4'',4'''-di-tert-butyl-2',2'',2'''trimethoxy-{4-(4'-diphenylaminophenyl)pyridine} were studied by ultra violet/ visible/ near infra red spectroscopy, cyclic voltammetry and ...
Bushby, R.J. +3 more
core +1 more source
Protein pyrophosphorylation by inositol pyrophosphates — detection, function, and regulation
Protein pyrophosphorylation is an unusual signaling mechanism that was discovered two decades ago. It can be driven by inositol pyrophosphate messengers and influences various cellular processes. Herein, we summarize the research progress and challenges of this field, covering pathways found to be regulated by this posttranslational modification as ...
Sarah Lampe +3 more
wiley +1 more source
2D Coordination Polymer [Fe(piv)2(dab)2]n
The interaction of preorganized iron(II) pivalate complexes with aromatic N-donor ligand (pyridine (py) or 2,2′-bipyridine (bpy)) and 1,4-diaminobutane (dab, putrescine) in anhydrous acetonitrile yielded a new 2D coordination polymer [Fe(piv)2(dab)2]n (1,
Vladimir A. Bushuev +4 more
doaj +1 more source
Matrix Assisted Formation of Ferrihydrite Nanoparticles in a Siloxane/Poly(Oxyethylene) Nanohybrid
Matrix-assisted formation of ferrihydrite, an iron oxide hydroxide analogue of the protein ferritin-core, in a sol-gel derived organic-inorganic hybrid is reported.
Amaral, Vitor S. +6 more
core +1 more source
We reconstituted Synechocystis glycogen synthesis in vitro from purified enzymes and showed that two GlgA isoenzymes produce glycogen with different architectures: GlgA1 yields denser, highly branched glycogen, whereas GlgA2 synthesizes longer, less‐branched chains.
Kenric Lee +3 more
wiley +1 more source
Sonochemical Synthesis of a New Nano Lead(II) Coordination Polymer with 2,5-bis(2-pyridyl)-3,4-diaza-2,4- hexadiene ligand: A Precursor to Produce Pure Phase Nano- sized Lead(II) Oxide [PDF]
A new nano-sized lead(II) coordination polymer, [Pb(2-bpdh)(NO3)2]n (1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene)}, was synthesized by a sonochemical method.
A. Morsali, L. Hashemi
doaj +1 more source
In the title compound, {[Cu2(C10H8O4)2(C14H14N4O2)]·5H2O}n, the CuII cations are coordinated in a square-pyramidal fashion, with four 3-(2-carboxyphenyl)propionate (cpp) carboxylate O-atom donors in the basal plane, along with an N-atom donor from a N-[2-
Gabrielle J. Gaskin, Robert L. LaDuca
doaj +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source
Neutral low-dimensional assemblies of a Mn(III) schiff base complex and octacyanotungstate(V) : synthesis, characterization, and magnetic properties [PDF]
International audienceTwo novel low-dimensional molecular magnetic materials were prepared by the self-assembly of 3d- and 5d-metal complexes. These are the first neutral heterobimetallic cyanobridged compounds involving one anisotropic Mn(III) Schiff ...
Majcher, Anna +3 more
core +1 more source

