Peptide‐Induced Ferroelectricity in Charge‐Transfer Supramolecular Materials
Bio‐inspired supramolecular charge‐transfer amphiphiles self‐assemble into nanoribbons in water, where peptide chirality‐induced symmetry breaking generates robust ferroelectricity across multiple systems. These water‐processable organic ferroelectrics also enhance neuronal outgrowth and electrophysiological maturity, offering a versatile strategy for ...
James V. Passarelli +15 more
wiley +1 more source
(E)-2-[4-(Diethylamino)styryl]-1-methylquinolin-1-ium 4-chlorobenzenesulfonate monohydrate
The asymmetric unit of the title hydrated salt, C22H25N2+·C6H4ClO3S−·H2O, comprises two 2-[4-(diethylamino)styryl]-1-methylquinolin-1-ium cations, two 4-chlorobenzenesulfonate anions and two solvent water molecules.
Suchada Chantrapromma +4 more
doaj +1 more source
Ultrasonic acoustic levitation for fast frame rate X-ray protein crystallography at room temperature
Increasing the data acquisition rate of X-ray diffraction images for macromolecular crystals at room temperature at synchrotrons has the potential to significantly accelerate both structural analysis of biomolecules and structure-based drug developments.
S. Tsujino, T. Tomizaki
semanticscholar +1 more source
Heptazine‐assisted MR‐TADF emitters enable narrowband yellow emission with high efficiency at high luminance in solution‐processed OLEDs. In doped films, HAP‐3CzBN achieves a record‐fast kRISC of 1.19 × 106 s−1. The optimized HAP‐3CzBN devices deliver 15.5% EQEmax with negligible roll‐off at 1000 cd m−2, 11.2% at 10,000 cd m−2, and a benchmark 20.3 ...
Changfeng Si +5 more
wiley +1 more source
Electron Transfer Prompted Ejection of a Tightly Bound K\u3csup\u3e+\u3c/sup\u3e from the Ethereal Cavity of a Hexaarylbenzene-Based Receptor [PDF]
Synthesis of a pair of rotamers (9u/9s) of a hexaarylbenzene derivative containing six (cofacially arranged) electroactive 2,5-dimethoxytolyl groups is described.
Lindeman, Sergey V. +2 more
core +1 more source
Asymmetry of the Ferroelectric Phase Transition in BaTiO3
Phase transitions are typically assumed to behave identically in forward and reverse. This work shows that in the ferroelectric material barium titanate this is not true: heating drives an abrupt, first‐order jump, while cooling gives a smooth, continuous change.
Asaf Hershkovitz +14 more
wiley +1 more source
(E)-4-Methoxy-N′-(2,4,5-trimethoxybenzylidene)benzohydrazide hemihydrate
The title compound crystallizes as a hemihydrate, C18H20N2O5·0.5H2O. The molecule exists in an E conformation with respect to the C=N imine bond. The 4-methoxyphenyl unit is disordered over two sets of sites with a refined occupancy ratio of 0.54 (2):0 ...
Suchada Chantrapromma +4 more
doaj +1 more source
Hexabenzo[4.4.4]propellane: A Helical Molecular Platform for the Construction of Electroactive Materials [PDF]
Helical hexabenzo[4.4.4]propellane (a relative of hexaphenylethane) and its derivatives are synthesized and their structures are established by X-ray crystallography.
Debroy, Paromita +2 more
core +1 more source
Phase Engineering of Nanogold: Non‐Close Packed Square Planes in A′B′ Stacking with a 0.5 Å Channel
Gold is well known to adopt the face‐centered‐cubic (fcc) structure. This work presents an unusual non‐close‐packed phase attained in a 40‐atom gold nanocluster, which is in contrast with the close‐packed fcc quasi‐isomer. The non‐compact structure exhibits exclusive square planes in a layer‐by‐layer stacking, hence, possessing a unique 0.5 Å channel ...
Yitong Wang +8 more
wiley +1 more source
(E)-1-(2,4-Dinitrophenyl)-2-(3-ethoxy-4-hydroxybenzylidene)hydrazine
The molecule of the title hydrazine derivative, C15H14N4O6, is essentially planar, the dihedral angle between the substituted benzene rings being 2.25 (9)°. The ethoxy and hydroxy groups are almost coplanar with their bound benzene ring [r.m.s. deviation
Hoong-Kun Fun +4 more
doaj +1 more source

