Synthesis, Structural Characterization, and Hirschfeld Surface Analysis of a New Cu(II) Complex and Its Role in Photocatalytic CO2 Reduction [PDF]
A new Cu(II) complex, [CuL1L2(CH3COO)2(H2O)]·H2O, was synthesized by the reaction of Cu(CH3COO)2·H2O, 6-phenylpyridine-2-carboxylic acid (HL1), and 4-[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]pyridine (L2) in ethanol-water (v:v = 1:1) solution.
Li-Hua Wang +3 more
doaj +2 more sources
Metal Complex Formation and Anticancer Activity of Cu(I) and Cu(II) Complexes with Metformin [PDF]
Metformin has been used for decades in millions of type 2 diabetes mellitus patients. In this time, correlations between metformin use and the occurrence of other disorders have been noted, as well as unpredictable metformin side effects. Diabetes is a significant cancer risk factor, but unexpectedly, metformin-treated diabetic patients have lower ...
Sherin Abdelrahman +5 more
openaire +5 more sources
Synthesis, characterization and biological studies complexes of Co(II), Ni(II), Cu(II) and Cd(II) with 5-(2-pyridyl)-2-(3,5-dinitro benzen)-1,3,4- oxadiazole ligand on McCoy cell [PDF]
In this research we report new complexes with the formula 5-(2-pyridyl)-2-(3,5-dinitro benzen)-1,3,4- oxadiazole ligand with Co(II), Ni(II), Cu(II) and Cd(II). These complexes were synthesized and characterized by IR spectroscopy, electronic spectroscopy,
Abolfazl Bezaatpour +4 more
doaj +1 more source
Synthesis, structural study and electrochemical properties of copper(II) complexes derived from benzene- and p-toluenesulphonylhydrazone [PDF]
The synthesis and characterization of benzene- and p-toluenesulphonylhydrazones derived from salicylaldehyde and 2-hydroxy-1-naphthaldehyde and their Cu(II) complexes are reported.
Larabi L. +3 more
doaj +1 more source
The reaction of N-(2-pyridyl)thiourea with CuCl2 in methanol yields four different crystalline products: yellow dimeric complex, [Cu2Cl2(µ-Cl)2(L)2] (1), red polymeric complex, [Cu3Cl8L2]n (2), orange crystalline product with ionic structure, L2[CuCl4 ...
Sara Tomšič +2 more
doaj +1 more source
Biologically active Cu(II) complex was synthesized from pyrimidine based Schiff base ligand 4-choloro-2-(((4,6-dimethoxypyrimidin-2-yl)imino)methyl)phenol.
Sahul Hameed Sukkur Saleem +6 more
doaj +1 more source
A hetero di-nuclear complex [Zn(o-phen)LCu(OAc)] (1) (H3L = o-HOC6H4CH = NNH)2C = O, o-phen = 1,10-phenanthroline) exhibited intercalative DNA binding (Kb = 1.03 × 105 M−1) as revealed from UV–Vis spectral analysis as well as viscosity study and further ...
Sidhali U. Parsekar +4 more
doaj +1 more source
Evaluation of antitumor potential of Cu(II) complex with hydrazone of 2-acetylthiazole and Girard’s t reagent [PDF]
In this paper, the previously synthesized Cu(II) complex ([CuL1(N3) (CH3OH)]BF4) with N,N,N-trimethyl-2-oxo-2-(2-(1-(thiazol-2-yl)ethylidene)- hydrazinyl)ethan-1-aminium chloride, has been characterized and its biological activity has been ...
Stevanović Nevena +8 more
doaj +1 more source
Correlation between UV-VIS spectra and the structure of Cu(II) complexes with hydrogenated dextran in alkaline solutions [PDF]
UV-VIS spectrophotometric investigations of Cu(II) complexes with hydroge-nated dextran showed that the complexation of Cu(II)-ions began at pH > 7. The formation of Cu(II) complexes with dextran monomer units was observed at pH 7-12.
Nikolić Goran S. +4 more
doaj +1 more source
New Ni (II) and Cu (II) complexes with pyridoxal-semicarbazone were synthesized and their structures were solved by X-ray crystallography. This analysis showed the bis-ligand octahedral structure of [Ni(PLSC-H)2]·H2O and the dimer octahedral structure of
Violeta Jevtovic +11 more
doaj +1 more source

