Studies Toward the Synthesis of a Novel Diastereomerically Pure Cyclopropyl N-Heterocyclic Carbene Ligand for Asymmetric Catalysis [PDF]
This M.S. Thesis research objective is designed towards the racemic synthesis of a novel diastereoselectively pure, sterically bulky, cyclopropyl-containing, N-heterocyclic carbene (NHC) ligand.
Milliken, Brandon T
core +1 more source
Biorenewable materials from isosorbide [PDF]
As petroleum feedstocks start to dwindle, it is becoming more important to find acceptable replacements for materials made from these feedstocks. Polyurethanes have classically been synthesized from petroleum-based feedstocks, and depending on its ...
Zenner, Michael Dennis
core +3 more sources
Rank Independence and Rearrangements of Random Variables [PDF]
A rearrangement of $n$ independent uniform $[0,1]$ random variables is a sequence of $n$ random variables $Y_1,...,Y_n$ whose vector of order statistics has the same distribution as that for the $n$ uniforms. We consider rearrangements satisfying the strong rank independence condition, that the rank of $Y_k$ among $Y_1,...,Y_k$ is independent of the ...
arxiv
A practical synthesis of enantiopure N-carbobenzyloxy-N′-phthaloyl-cis-1,2-cyclohexanediamine by asymmetric reductive amination and the Curtius rearrangement [PDF]
Jun‐ichi Matsuo+4 more
openalex +1 more source
Synthesis of a Glutathione Analogue Using 2-α-Methyl-β-Cysteine [PDF]
Inhibitors of glutathione reductase (GR) have been synthesized and studied in order to reverse an increasing trend in resistance to common malaria treatments.
Freeman, Nathan
core +1 more source
Rearrangements of gaussian fields [PDF]
The monotone rearrangement of a function is the non-decreasing function with the same distribution. The convex rearrangement of a smooth function is obtained by integrating the monotone rearrangement of its derivative. This operator can be applied to regularizations of a stochastic process to measure quantities of interest in econometrics.
arxiv
Synthesis of Substituted Benzoxazolinones by the Curtius Rearrangement: Crystal Structures of Intermediates and By-Products [PDF]
Gerhard Laus+4 more
openalex +1 more source
N-Acylbenzotriazoles as Proficient Substrates for an Easy Access to Ureas, Acylureas, Carbamates, and Thiocarbamates via Curtius Rearrangement Using Diphenylphosphoryl Azide (DPPA) as Azide Donor [PDF]
Vinod K. Tiwari+4 more
openalex +1 more source
A rearrangement step with potential uses in priority queues [PDF]
Link-based data structures, such as linked lists and binary search trees, have many well-known rearrangement steps allowing for efficient implementations of insertion, deletion, and other operations. We describe a rearrangement primitive designed for link-based, heap-ordered priority queues in the comparison model, such as those similar to Fibonacci ...
arxiv
Strict rearrangement inequalities: nonexpansivity and periodic Gagliardo seminorms [PDF]
This paper deals with the behavior of the periodic Gagliardo seminorm under two types of rearrangements, namely under a periodic, and respectively a cylindrical, symmetric decreasing rearrangement. Our two main results are P\'olya-Szeg\H{o} type inequalities for these rearrangements. We also deal with the cases of equality.
arxiv