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Free-Radical Deoxygenative Amination of Alcohols via Copper Metallaphotoredox Catalysis. [PDF]

J Am Chem Soc
Carson WP, Tsymbal AV, Pipal RW, Edwards GA, Martinelli JR, Cabré A, MacMillan DWC.   +6 more
europepmc   +1 more source

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Theoretical insights into photo-induced Curtius rearrangement of chlorodifluoroacetyl azide

Organic Chemistry Frontiers, 2017
The mechanism of photo-induced Curtius rearrangement is a two-step reaction with a nitrene intermediate.
Xing-Liang Peng, Wei-Lu Ding, Quan-Song Li   +2 more
exaly   +4 more sources

Theoretical study on the photochemistry of furoylazides: Curtius rearrangement and subsequent reactions

Physical Chemistry Chemical Physics, 2020
Theoretical calculations obtained new insights into the photochemistry of furoylazides and nitrenes.
Jian Li, Meng-Kai Liu, Quan-Song Li, Ze-Sheng Li   +3 more
openaire   +4 more sources

Catalyst-Free Cyclization- and Curtius Rearrangement-Induced Functional Group Transformation: An Improved Synthetic Strategy of First-in-Class ATX Inhibitor Ziritaxestat (GLPG-1690)

Organic Process Research and Development, 2020
A practical and highly efficient protocol for the production of Autotaxin (ATX) inhibitor Ziritaxestat (1) was described.
Yu Yang, Nan Jiang, Ping Gong
exaly   +2 more sources

An Improved Synthesis of Urea Derivatives from N-Acylbenzotriazole via Curtius Rearrangement

Synthesis, 2019
The good leaving tendency of the benzotriazole moiety has been exploited for the synthesis of symmetric, unsymmetric, N-acyl, and cyclic ureas in good yields from N-acylbenzotriazoles by treating the latter with various amines in the presence of TMSN3 ...
Vinod K Tiwari
exaly   +2 more sources

The Aza Curtius Rearrangement

European Journal of Organic Chemistry, 2001
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Alexander N. Chernega, I. I. Maletina, Eduard B. Rusanov, Lev M. Yagupolskii, Svetlana V. Shelyazhenko, Vitalij N. Petrik   +5 more
openaire   +4 more sources

Azide monoliths as convenient flow reactors for efficient Curtius rearrangement reactions

Organic and Biomolecular Chemistry, 2008
The preparation and use of an azide-containing monolithic reactor is described for use in a flow chemistry device and in particular for conducting Curtius rearrangement reactions via acid chloride inputs.
Marcus Baumann, Ian Baxendale, Steven V Ley   +2 more
exaly   +4 more sources

A modular flow reactor for performing Curtius rearrangements as a continuous flow process

Organic and Biomolecular Chemistry, 2008
The use of a mesofluidic flow reactor is described for performing Curtius rearrangement reactions of carboxylic acids in the presence of diphenylphosphoryl azide and trapping of the intermediate isocyanates with various nucleophiles.
Marcus Baumann, Ian Baxendale, Steven V Ley   +2 more
exaly   +4 more sources