Results 151 to 160 of about 269,189 (237)
Some of the next articles are maybe not open access.

Theoretical insights into photo-induced Curtius rearrangement of chlorodifluoroacetyl azide

Organic Chemistry Frontiers, 2017
The mechanism of photo-induced Curtius rearrangement is a two-step reaction with a nitrene intermediate.
Xing-Liang Peng   +2 more
exaly   +4 more sources

Theoretical study on the photochemistry of furoylazides: Curtius rearrangement and subsequent reactions

Physical Chemistry Chemical Physics, 2020
Theoretical calculations obtained new insights into the photochemistry of furoylazides and nitrenes.
Jian Li   +3 more
openaire   +4 more sources

A modular flow reactor for performing Curtius rearrangements as a continuous flow process

Organic and Biomolecular Chemistry, 2008
The use of a mesofluidic flow reactor is described for performing Curtius rearrangement reactions of carboxylic acids in the presence of diphenylphosphoryl azide and trapping of the intermediate isocyanates with various nucleophiles.
Marcus Baumann   +2 more
exaly   +4 more sources

DMAP Catalyzed One-Pot Curtius Rearrangement Using 1,1-Dimethyl-2,2,2-trichloroethoxycarbonyl Azide.

Organic Letters, 2023
We report our development of a controllable, base-free, one-pot Curtius rearrangement using 1,1-dimethyl-2,2,2-trichloroethoxycarbonyl azide (DMTN3) with 4-(dimethylamino)pyridine (DMAP) as a catalyst.
Ken-Ching Lin, Hongjian Lu
semanticscholar   +1 more source

Accessing Highly Oxidized Imidazolidinone Cores via a Curtius Rearrangement: Total Synthesis of Colensolide A.

Organic Letters, 2023
The hydroxytetrahydropyrrolo-imidazolidinone (HTHP-I) core present in colensolide A is a synthetically intriguing scaffold as a result of its high heteroatom/carbon ratio and perceived instability.
Evan Savelson, J. Tepe
semanticscholar   +1 more source

Curtius-rearrangement of “rigid” azides

open access: closedTetrahedron Letters, 1964
Walter Lwowski   +3 more
openalex   +3 more sources

KINETICS AND MECHANISM OF THE CURTIUS REARRANGEMENT OF m-NITROBENZOYL AZIDE IN AQUEOUS SOLUTIONS OF SULFURIC ACID

Bulletin of the Saint Petersburg State Institute of Technology (Technical University), 2022
The kinetics and mechanism of the Curtius rearrangement of m-nitrobenzoyl azide in aqueous solutions of sulfuric acid of various concentrations has been studied.
Yuliya N. Pavlyukova   +2 more
semanticscholar   +1 more source

Synthesis of New Dialkyl 2,2′-[Carbonylbis(azanediyl)]dibenzoates via Curtius Rearrangement

Synthesis, 2021
The 2-(alkylcarbonyl)benzoic acids obtained by esterification of phthalic anhydride are converted into azide derivatives: alkyl 2-[(azidocarbonyl)amino]benzoates and to ureas: dialkyl 2,2′-[carbonylbis(azanediyl)]dibenzoates.
M. Khouili   +7 more
semanticscholar   +1 more source

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