Do one‐step mechanisms always involve simultaneous evolution of electron density? QTAIM/IQA analysis of the Curtius rearrangement [PDF]
, 2020 The Curtius rearrangement reaction is studied by using quantum theory of atoms in molecules (QTAIM) analysis of the electron density and the interacting quantum atoms (IQA) formalism.
José L. López‐Fernández +2 more
openalex +3 more sources
The Curtius rearrangement of cyclopropyl and cyclopropenoyl azides. A combined theoretical and experimental mechanistic study. [PDF]
J Org Chem, 2008 Tarwade V, Dmitrenko O, Bach RD, Fox JM.
europepmc +3 more sources
Photoinduced, Copper-Catalyzed Decarboxylative C-N Coupling to Generate Protected Amines: An Alternative to the Curtius Rearrangement. [PDF]
J Am Chem Soc, 2017 Zhao W, Wurz RP, Peters JC, Fu GC.
europepmc +3 more sources
Oxidative N−N Bond Formation Versus the Curtius Rearrangement
Chemistry – A European JournalAbstractThe oxidative formation of N−N bonds from primary amides has been recently reported and then retracted in the journal Nature Communications by Kathiravan, Nicholls, and co‐authors, utilizing a hypervalent iodane reagent. Unfortunately, the authors failed to recognize the Curtius reaction taking place under the described reaction conditions ...
Melissa Hohenadel +3 more
openalex +4 more sources
Interrupted Curtius Rearrangements of Quaternary Proline Derivatives: A Flow Route to Acyclic Ketones and Unsaturated Pyrrolidines. [PDF]
J Org Chem, 2021 Baumann M, Moody TS, Smyth M, Wharry S.
europepmc +3 more sources
The Use of Tetrabutylammonium Azide in the Curtius Rearrangement. [PDF]
Acta Chemica Scandinavica, 1974 Arne Brändström +5 more
openalex +3 more sources
Pyridone annulation via tandem Curtius rearrangement/6π-electrocyclization: total synthesis of (-)-lyconadin C. [PDF]
Org Lett, 2013 Cheng X, Waters SP.
europepmc +3 more sources
An ( R )-4-Phenyl-1,3-oxazolidine-2-Thione Mediated Approach to 2, 3-Disubstituted Oxetanes and the Key Hydroxyethyl Isostere of the Hiv Protease Inhibitor Darunavir. Preparation of Non-evans Syn Glycolate Aldol Addition Products. a New Direction for the Curtius Rearrangement in the Dehomologation of Alpha-alkoxycarboxylic Acids [PDF]
, 2023 Since the emergence of AIDS in the early 1980s, strategies to mitigate the disease remain a high priority for medical professionals worldwide. While there is no broadly available cure or vaccine for HIV/AIDS at this time, early diagnosis and treatment ...
Jordan Witte
openalex +3 more sources
Hyphenating the curtius rearrangement with Morita-Baylis-Hillman adducts: synthesis of biologically active acyloins and vicinal aminoalcohols [PDF]
, 2011 Giovanni W. Amarante +2 more
openalex +3 more sources
Rapid and Scalable Halosulfonylation of Strain‐Release Reagents**
Angewandte Chemie, Volume 135, Issue 3, January 16, 2023., 2023 A one‐pot halosulfonylation of strained hydrocarbons is described that proceeds under practical, scalable and mild conditions. Sulfonyl halides featuring aryl, heteroaryl and alkyl substituents are generated in situ from sulfinate salts and convenient halogen atom sources. This chemistry enables the synthesis of an array of halogen/sulfonyl‐substituted
Helena D. Pickford +7 more
wiley +2 more sources