Do one‐step mechanisms always involve simultaneous evolution of electron density? QTAIM/IQA analysis of the Curtius rearrangement [PDF]
The Curtius rearrangement reaction is studied by using quantum theory of atoms in molecules (QTAIM) analysis of the electron density and the interacting quantum atoms (IQA) formalism.
José L. López‐Fernández+2 more
semanticscholar +4 more sources
N,N′-Dibenzylethylenediammonium dichloride [PDF]
The isolation and crystalline structure of N,N′-dibenzylethylenediammonium dichloride, C16H22N22+·2Cl−, is reported. This was obtained as an unintended product of an attempted Curtius rearrangement that involved benzylamine as one of the reagents and 1,2-
Mary Helene Marmande+3 more
doaj +2 more sources
Novel Inhibitors of Acetyl- and Butyrylcholinesterase Derived from Benzohydrazides: Synthesis, Evaluation and Docking Study [PDF]
On the basis of previous reports, novel 2-benzoylhydrazine-1-carboxamides were designed as potential inhibitors of acetylcholinesterase (AChE) and butyrylcholinesterase (BChE). Inhibitors of these enzymes have many clinical applications.
Neto-Honorius Houngbedji+6 more
doaj +2 more sources
Coupling biocatalysis with high-energy flow reactions for the synthesis of carbamates and β-amino acid derivatives [PDF]
A continuous flow process is presented that couples a Curtius rearrangement step with a biocatalytic impurity tagging strategy to produce a series of valuable Cbz-carbamate products.
Alexander Leslie+4 more
doaj +2 more sources
Curtius rearrangement and Wolff homologation of functionalized peroxides
AbstractFor Abstract see ChemInform Abstract in Full Text.
Patrick H. Dussault, Chunping Xu
openalex +5 more sources
Tandem Continuous Flow Curtius Rearrangement and Subsequent Enzyme-Mediated Impurity Tagging [PDF]
The use of continuous flow as an enabling technology within the fine chemical and pharmaceutical industries continues to gain momentum.
M. Baumann+4 more
semanticscholar +3 more sources
The shortest synthesis of N-protected 1′-aminoferrocene-1-carboxylic acid from readily available ferrocene-1,1′-dicarboxylic acid is reported.
William Erb+3 more
openalex +3 more sources
Curtius Rearrangement of Aromatic Carboxylic Acids to Access Protected Anilines and Aromatic Ureas. [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
H. Lebel, Olivier Leogane
openalex +5 more sources
The Curtius rearrangement of cyclopropyl and cyclopropenoyl azides. A combined theoretical and experimental mechanistic study. [PDF]
Tarwade V, Dmitrenko O, Bach RD, Fox JM.
europepmc +3 more sources