[(Cp-R)M(CO)3] (M= Re or 99mTc) Conjugates for Theranostic Receptor Targeting
CHIMIA, 2013 Cyclopentadienyl complexes of 99mTc became accessible via a retro Diels-Alder synthetic approach of dimerized cyclopentadiene derivatives. So far, this approach was limited to derivatives comprising a carboxylic acid group, directly conjugated ...
Daniel Can +4 more
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A Simple Approach for Visual Rearrangement: 3D Mapping and Semantic Search [PDF]
arXiv, 2022 Physically rearranging objects is an important capability for embodied agents. Visual room rearrangement evaluates an agent's ability to rearrange objects in a room to a desired goal based solely on visual input. We propose a simple yet effective method for this problem: (1) search for and map which objects need to be rearranged, and (2) rearrange each
arxiv
Acta Crystallographica Section E: Crystallographic Communications, 2019 1′-Aminocobaltocenium-1-carboxylic acid chloride, [Co(C5H6N)(C6H5O2)]Cl·H2O, (3), and its azo derivative 1′-[2-(1-amino-2,6-dimethylphenyl)diazen-1-yl]cobaltocenium-1-carboxylic acid hexafluoridophosphate, [Co(C13H14N3)(C6H5O2)]PF6·H2O (5) were obtained ...
Markus Jochriem +3 more
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New approaches to amino-pyrrolidine guanidine compounds [PDF]
, 2021 Cernumidine is an alkaloid of natural origin isolated from the plant Solanum cernuum Vell with the ability to inhibit the production of IL-8 from HT-29 colon carcinoma.
Leitão, Flávia Lidónio
core
Arabian Journal of Chemistry, 2021 Herein, we describe the synthesis of novel piperidinyl thieno tetrahydroisoquinolines attached or fused to other new heterocycles. The diazotization of the previously synthesized pyrrolyl carbohydrazide 1 followed by several reactions with ethanol ...
Remon M. Zaki +4 more
doaj
Lossen Rearrangement Reaction of Aromatic and Aliphatic Hydroxamates [PDF]
, 2016 The main goal of this research is to explore a potential of the most green and non-toxic possible route to the synthesis of industrially important chemicals, such as isocyanates and amines, based on the bio-based starting materials.
Sanaallah, Mirvat
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The Synthesis and Characterization of the 2,2\u27-Bisacylazide of 3,3\u27-Bipyridine [PDF]
, 1972 The primary objective of this research has been the synthesis and characterization of a new heterocyclic diacylazide, the 2,2\u27-bisacylazide of 3,3\u27-bipyridine 19.
El-Fayoumy, Magdy Adly Guirguis
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An alternative approach to aminodiols from Baylis-Hillman adducts: stereoselective synthesis of chloramphenicol, fluoramphenicol and thiamphenicol [PDF]
, 2015 We describe herein a new approach for the stereoselective synthesis of broad spectrum antibiotics from Baylis-Hillman adducts. The strategy is based on the preparation of an ene-carbamate directly from a Baylis-Hillman adduct using a Curtius ...
Coelho, Fernando, Mateus, Cristiano R.
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Boranes in Organic Chemistry 2. ОІ-Aminoalkyl- and ОІ-Sulfanylalkylboranes in Organic Synthesis
Eurasian Chemico-Technological Journal, 2002 Problems on using of ОІ-aminoalkyl- and ОІ-sulfanylalkylboranes in organic synthesis are considered in this review. The synthesis of boron containing a-aminoacids by Curtius rearrangement draws attention.
V.M. Dembitsky +2 more
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Redefining the Scope of the Curtius Reaction via a Dehomologation of Carboxylic Acids Bearing an Alpha Leaving Group. Determining the Stereoelectronic Limitations of the Crimmins Anti-selective Asymmetric Glycolate Aldol Addition Reaction. [PDF]
The Curtius rearrangement is an important synthetic transformation in organic chemistry and is named in honor of Theodore Curtius who developed this reaction in the late 19th century.
Odeh, Joy
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