Reactive & Efficient: Organic Azides as Cross-Linkers in Material Sciences
Molecules, 2020 The exceptional reactivity of the azide group makes organic azides a highly versatile family of compounds in chemistry and the material sciences. One of the most prominent reactions employing organic azides is the regioselective copper(I)-catalyzed ...
Marvin Schock, Stefan Bräse
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SmI<sub>2</sub>-Catalyzed Coupling of Alkyl Housane Ketones and Alkenes in an Approach to Norbornanes. [PDF]
Angew Chem Int Ed EnglSamarium diiodide (Sml2) is an effective catalyst for the mild, atom‐economical coupling of bicyclo[2.1.0]pentane, or housane, ketones, and electron‐deficient alkenes to give functionalized norbornane structural motifs not easily accessible by classical cycloaddition approaches.
Roy D +7 more
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Mechanochemical reactions studied by in situ Raman spectroscopy : base catalysis in liquid-assisted grinding [PDF]
, 2015 In situ Raman spectroscopy was employed to study the course of a mechanochemical nucleophilic substitution on a carbonyl group.
Biliškov, Nikola +8 more
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Triazolinediones as highly enabling synthetic tools [PDF]
, 2016 Triazolinediones (TADs) are unique reagents in organic synthesis that have also found wide applications in different research disciplines, in spite of their somewhat "exotic" reputation.
Billiet, Stijn +5 more
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A THEORETICAL STUDY OF THE THERMAL CURTIUS REARRANGEMENT OF SOME CINNAMOYL AZIDES USING THE DFT APPROACH [PDF]
Journal of Structural Chemistry, 2015 R. Abu-Eittah, W. Hassan, W. Zordok
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A short synthesis of (±)-cherylline dimethyl ether
Beilstein Journal of Organic Chemistry, 2009 A synthesis of (±)-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet–Spengler cyclization.
Bhima Y. Kale +7 more
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Synthesis of N-Z, N′-Formyl α-Amino Acid Derived Gem-Diamines [PDF]
, 2008 A variety of N-carbobenzoxy, N′-formyl gem-diaminoalkyl derivatives have been obtained through Goldsmith-Wick reaction of Z-α-amino acid/peptide acid derived isocyanates with 96% HCOOH in presence of 4-dimethylaminopyridine (DMAP) as catalyst.
Narendra, N., Sureshbabu, V.V.
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Convenient Synthesis and Antimicrobial Activity of Some Novel Amino Acid Coupled Triazoles
Molecules, 2010 This study describes a promising one-pot synthesis of [2-(5-benzyl-4-phenyl-4H-[1,2,4]triazol-3-thio)-acetyl]-amino acid methyl esters 6a-h and dipeptides 10a-e, which were successfully synthesized starting from amino acid esters 5a-h, 9a-e and azides 4,
S. M. El Rayes
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Some Applications of the Curtius Rearrangement
Journal of the Chemical Society, Perkin Transactions 1, 1983 Pairs of optically pure enantiomers of substituted 1,1 -diamines have been prepared from the azides of L-amino-acids via the Curtius rearrangement.This synthesis is based on the interchange of two groups attached to the asymmetrically substituted tetrahedral α-carbon atom of the parent amino acid.
Moutevelis-Minakakis, P., Photaki, I.
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T3P® (propylphosphonic anhydride) Mediated Conversion of Carboxylic Acids into Acid Azides and one-pot Synthesis of Ureidopeptides [PDF]
, 2010 A general, mild, efficient, and environmentally benign protocol, which makes use of T3P® as an acid activating agent for the direct synthesis of acid azides from carboxylic acids is described.
Basavaprabhu, . +3 more
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