Results 61 to 70 of about 8,110 (222)

Rearrangement groups of fractals [PDF]

open access: yesTransactions of the American Mathematical Society 372.7 (2019): 4509-4552, 2015
We construct rearrangement groups for edge replacement systems, an infinite class of groups that generalize Richard Thompson's groups F, T, and V . Rearrangement groups act by piecewise-defined homeomorphisms on many self-similar topological spaces, among them the Vicsek fractal and many Julia sets.
arxiv   +1 more source

Facile and One-pot Synthesis of Nα-fmoc/bsmoc/boc/z-protected Ureidopeptides and Peptidyl Ureas Employing Diphenylphosphoryl Azide [DPPA] [PDF]

open access: yes, 2008
Diphenylphosphoryl azide (DPPA) mediated one-pot synthesis of Nα-Fmoc/Bsmoc/Boc/Z-protected ureidopeptides and peptidyl ureas as well as phenyl/succinimidyl (Nα-urethane protected) methyl carbamates starting from Nα-protected amino acids is reported. The
Chennakrishnareddy, G.   +2 more
core   +3 more sources

Derivatizing immobilization methods for TEMPO radicals in metal–organic frameworks: Toward efficient aerobic oxidation and sequential reactions

open access: yesBulletin of the Korean Chemical Society, EarlyView.
Covalent attachment of TEMPO radicals to Zr‐based metal–organic frameworks (MOFs) was achieved by diversifying linker structures, enabling efficient aerobic oxidation of secondary alcohols. The modified MOFs facilitated sequential reactions, including isoxazole synthesis via aerobic oxidation and cycloaddition, demonstrating their versatility and ...
Seungheon Cha   +7 more
wiley   +1 more source

Fully Renewable Non-Isocyanate Polyurethanes via the Lossen Rearrangement [PDF]

open access: yes, 2020
In this work, a straightforward and efficient synthesis approach to renewable non‐isocyanate polyurethanes (NIPUs) is described. For this purpose, suitable and renewable carbamate monomers, possessing two double bonds, are synthesized from hydroxamic ...
Filippi, Luca, Meier, Michael A. R.
core   +2 more sources

Strategy‐Level Prodrug Synthesis

open access: yesChemistry – A European Journal, Accepted Article.
Organic synthesis uniquely provides opportunities to access molecules that serve defined purposes. Medicinal chemistry illustrates this attribute well with prodrug design, whereby a drug undergoes a late‐stage conversion to a conditionally responsive active medicinal agent (AMA), being a notable example.
Paul Geaneotes, Paul Floreancig
wiley   +1 more source

The Dihydroindeno[2,1‐c]fluorene Core: from Syntheses to Properties and Potential Applications

open access: yesEuropean Journal of Organic Chemistry, Accepted Article.
In the last decade, substances possessing the dihydroindeno[2,1‐c]fluorene scaffold showed interesting photo‐physical properties and other potential applications in electronics. The afore‐mentioned compounds belong to the family of five regioisomeric dihydroindenofluorenes, but unlike other ones, they possess angular or, in the case of higher congeners,
Timothée Cadart, Martin Kotora
wiley   +1 more source

Aminoisothiazolamides, a new class of potent inhibitors of lysyl‐tRNA synthetase

open access: yesPest Management Science, EarlyView.
The present work covers a series of novel herbicidal lead structures that possess an aminoisothiazolamide scaffold as a structural key feature. Lysyl‐tRNA synthetase 1 (KRS1) was identified as the biochemical mode‐of‐action. Based on optimized and tailored synthetic approaches, a broader SAR study was carried out delivering some lead structures that ...
David Bernier   +26 more
wiley   +1 more source

Funcionalització d’enllaços C–H catalitzada per pal·ladi per a la síntesi de tetrahidroisoquinolines [PDF]

open access: yes, 2022
Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2022. Tutor: Xavier Ariza PiquerThe synthesis of new bioactive compounds is always a challenge for chemists, particularly in areas where the appearance of resistant ...
Guillamon Daimiel, Pau
core  

Synthetic approaches towards alkaloids bearing α-tertiary amines [PDF]

open access: yes, 2016
Alkaloids account for some of the most beautiful and biologically active natural products. Although they are usually classified along biosynthetic criteria, they can also be categorized according to certain structural motifs.
Hager, Anastasia   +4 more
core   +3 more sources

Analysis of cooperativity and localization for atomic rearrangements [PDF]

open access: yes, 2004
We propose new measures of localization and cooperativity for the analysis of atomic rearrangements. We show that for both clusters and bulk material cooperative rearrangements usually have significantly lower barriers than uncooperative ones, irrespective of the degree of localization.
arxiv   +1 more source

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