Results 151 to 160 of about 4,145 (241)

Catalytic C–F Bond Activation at Room Temperature: Enolate Cross‐Couplings Enabled by [Pd(1‐MeNAP)TFA]2 and LiHMDS

open access: yesAngewandte Chemie International Edition, EarlyView.
Catalysts generated from the trifluoroacetate‐bridged methylnaphthyl‐palladium dimer [Pd(1‐MeNAP)TFA]2 and biarylphosphine ligands in combination with the base LiHMDS promote α‐arylation reactions of various enolates with non‐activated aryl fluorides at room temperature.
Nele Krüger   +4 more
wiley   +1 more source

Hydrogen Permeability of Tubular Polymer Membranes for Biological Methanation Membrane Reactors

open access: yesJournal of Applied Polymer Science, EarlyView.
A reproducible method for permeability measurements of tubular polymer membranes is developed and combined with a comprehensive review of hydrogen permeability data. Based on this analysis, a suitable tubular polymer membrane is identified for application in biological methanation within membrane reactors.
Maximilian Peter Mock   +3 more
wiley   +1 more source

Changing a Winning Team—Replacement of Brominated Flame Retardant and Antimony Trioxide in Acrylonitrile–Butadiene–Styrene

open access: yesJournal of Applied Polymer Science, EarlyView.
This comprehensive study investigates reducing the amount of brominated flame retardant (Br) and/or antimony trioxide (ATO) in acrylonitrile–butadiene–styrene. Therefore, condensed‐phase flame‐retardant mechanisms are introduced into the flame‐inhibition system.
Sebastian M. Goller   +2 more
wiley   +1 more source

Synthesis of a Novel Amine‐Based Curing Agent for Epoxy Resins Derived From Vanillin

open access: yesJournal of Applied Polymer Science, EarlyView.
The four‐step synthesis of a new bio‐based amine hardener is described starting from vanillin as a bio‐based compound. The hardener ADBA was utilized to cure DGEBA and the resulting Tg,tanδmax was determined via DMA. Compared to other bio‐based curing agents, our curing agent is obtainable in a high yield and leads to a superior Tg of 135°C.
Bastian Hahn   +3 more
wiley   +1 more source

In Situ Generation of a Robust Gel Polymer Electrolyte From a Poly(Ethylene Carbonate)‐Hydrogenated Nitrile Butadiene Rubber Containing Thermoplastic Vulcanizate Electrolyte

open access: yesJournal of Applied Polymer Science, EarlyView.
A gel polymer electrolyte thermoplastic vulcanizate (GPE–TPV) was prepared by blending HNBR and PEC by melt extrusion then thermally decomposing PEC to yield liquid EC. EC is absorbed into the crosslinked HNBR, yielding an electrolyte that is mechanically and electrochemically stable enough to permit cycling in a LiFePO4–Li half‐cell.
Rozita Sadeghzadeh   +5 more
wiley   +1 more source

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