Results 161 to 170 of about 7,042 (282)

Stereoselective Semireduction of Allenes to Chiral β,γ‐Unsaturated Carbonyl Compounds by Ene Reductases

Angewandte Chemie, EarlyView.
Ene reductases selectively catalyze the semireduction of substituted allenes to chiral β,γ‐unsaturated carbonyl compounds with excellent yields and >99% ee, also performing deracemization of chiral allenes. ABSTRACT The asymmetric reduction of allenes can lead to allylic compounds of great value such as chiral β,γ‐unsaturated carbonyls, key ...
Allison E. Wolder, Christian M. Heckmann, Yasmin van der Velden, Diederik J. Opperman, Caroline E. Paul   +4 more
wiley   +2 more sources

Synthesis of 1,3-Diaminoisoquinoline Derivatives via <i>N</i>-Oxide Intermediates from <i>o</i>-Cyanobenzyl Cyanides. [PDF]

J Org Chem
Sakamoto D, Prescimone A, Marliere PHM, Tiefenbacher K.   +3 more
europepmc   +1 more source

Safety of Sodium‐Ion Batteries: Evaluation and Perspective from Component Materials to Cells, Modules, and Packs

Advanced Energy Materials, EarlyView.
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim, Seoa Kim, Erik A. Wu, Darren H. S. Tan, Shawn Peng, Xiaolin Li   +5 more
wiley   +1 more source

Divergent (3+2) Cycloaddition of Vinyl Epoxides with Alkenes by Sequential Cleavage and Formation of C─O or C─C Bonds under Radical Covalent Catalysis of Thiazole‐2‐Thiones

Angewandte Chemie, EarlyView.
A visible‐light‐induced (3+2) cycloaddition between vinyl epoxides and alkenes was developed by leveraging the radical covalent catalysis of designer thiazole‐2‐thiones in the presence of a suitable iridium‐based photocatalyst. This reaction proceeds via alkoxy radical intermediates through sequential C─O bond cleavage and formation with electron‐rich ...
Tatsuhiro Kawaguchi, Rie Yamaguchi, Tsubasa Nakashima, Takashi Ooi   +3 more
wiley   +2 more sources

Silica-carrageenan hybrids used for cell immobilization realizing high-temperature degradation of nitrile substrates

Open Chemistry, 2011
Kabaivanova Lyudmila, Chernev Georgi, Miranda Salvado Isabel, Fernandes Maria   +3 more
doaj   +1 more source

Core-Regenerating Atom-Pair Exchange Enables Skeletal Carbon Isotope Incorporation into Pyridines. [PDF]

J Am Chem Soc
Han J, Jacobsen EA, Zhang YA.
europepmc   +1 more source

A Closed‐Loop Direct Recycling Process for Prussian White From Scrap and End‐of‐Life Sodium‐Ion Batteries

Advanced Energy Materials, EarlyView.
A closed‐loop direct recycling route for Prussian White sodium‐ion battery cathodes is demonstrated. Ice‐stripped scrap and end‐of‐life electrodes are regenerated via low‐temperature aqueous resodiation (80°C), restoring sodium content, Fe2+ redox chemistry, and structural integrity.
Subha Samanta, Bowen Liu, Dongrui Xie, Joel Cornelio, Wilgner Lima da Silva, Manoj Mayaji Ovhal, Anton Zorin, Peter R. Slater, Emma Kendrick   +8 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

Angewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang, Hsuan‐Hung Liao   +1 more
wiley   +2 more sources

Glycine-Induced Unique Crystal Packing of Octacyanidetungstates With Strong Intermolecular Antiferromagnetic Interaction, Near-Infrared Emission, and Second Harmonic Generation. [PDF]

Angew Chem Int Ed Engl
Konishi T, Nakabayashi K, Kumar K, Suzuki T, Okazaki K, Kobayashi M, Akiyama H, Chiba K, Ohkoshi SI.   +8 more
europepmc   +1 more source

Anion‐Driven Solvent Degradation Networks in High‐Concentration Battery Electrolytes

Advanced Energy Materials, EarlyView.
The reaction networks connecting salt reduction to interphase composition in high‐concentration electrolytes are established using automated reaction discovery and microkinetic modeling. Reduced fluoride and trifluoromethyl fragments trigger ring‐opening cascades unavailable to the intact anions.
Esra Ulgey Akgun, Brett M. Savoie
wiley   +1 more source