Results 221 to 230 of about 157,130 (323)
Rapid access to the core of malayamycin A by intramolecular dipolar cycloaddition. [PDF]
Liu Y +5 more
europepmc +1 more source
Cationic Polar Cycloaddition with a-Chlorosulfides
Hiroyuki Ishibashi +4 more
openalex +1 more source
Gold(I)‐Catalyzed Domino Cyclization for the Construction of Trispirocyclic Cyclohexanes
We describe herein a series of intricate trispirocyclic architectures that have been synthesized from readily available substrates through an operationally simple one‐pot transformation under mild conditions. An unprecedented gold(I)‐catalyzed domino cyclization involving 2‐ethynylbenzyl alcohol derivatives and heterocyclic α,β‐unsaturated imines ...
Manon Genet +3 more
wiley +1 more source
Lewis Acid-Catalyzed Divergent (4+3)/(4+2) Annulations of <i>o</i>-Quinone Methides with Bicyclo[1.1.0]butanes Lead to sp<sup>3</sup>-Rich Oxabicyclic Frameworks. [PDF]
Mondal S +4 more
europepmc +1 more source
Intramolecular N···F Pnictogen Bond Mitigates the Explosive Behavior of Azido‐L‐Phenylalanines
An intramolecular N···F pnictogen bond is the key for the chemical stabilization of the fluorinated azido‐L‐phenylalanines, mitigating the risk of explosion and thus facilitating the handling and storage of these materials. Organic azides are versatile intermediates but are plagued by intrinsic instability and potential explosiveness. Here, it is shown
Andrea Pizzi +5 more
wiley +1 more source
Cycloaddition and functionalization reactions involving tropone. [PDF]
Doraghi F +3 more
europepmc +1 more source
Recent Advances in the Synthesis of 2-Substituted Oxetanes [PDF]
Bull, JA, Davis, O
core +1 more source
The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank +6 more
wiley +1 more source

