Results 21 to 30 of about 14,856 (220)

3-(2,6-Dioxopiperidin-3-yl)-3-azabicyclo[3.2.0]heptane-2,4-dione

open access: yesActa Crystallographica Section E, 2009
The title molecule, C11H12N2O4, consists of a 3-azabicyclo[3.2.0]heptane group containing a nearly planar cyclobutane ring (r.m.s. deviation of fitted atoms is 0.0609 Å), fused to a pyrrolidine ring, bonded to a 2,6-dioxopiperidine ring at the
Jerry P. Jasinski   +4 more
doaj   +1 more source

Supramolecular Sandwiches: Halogen-Bonded Coformers Direct [2+2] Photoreactivity in Two-Component Cocrystals

open access: yesMolecules, 2020
The halogen-bond (X-bond) donors 1,3- and 1,4-diiodotetrafluorobenzene (1,3-di-I-tFb and 1,4-di-I-tFb, respectively) form cocrystals with trans-1,2-bis(2-pyridyl)ethylene (2,2′-bpe) assembled by N···I X-bonds.
Jay Quentin   +2 more
doaj   +1 more source

Stereocontrolled Synthesis and Functionalization of Cyclobutanes and Cyclobutanones

open access: yesMolecules, 2013
In the last decade a certain number of new cyclobutane and cyclobutanone synthesis and functionalization protocols have been published. Organo- and biocatalyzed eco-friendly approaches to cyclobutane-containing molecules have been developed with ...
Francesco Secci   +2 more
doaj   +1 more source

Halogen-bonded zigzag molecular network based upon 1,2-diiodoperchlorobenzene and the photoproduct rctt-1,3-bis(pyridin-4-yl)-2,4-diphenylcyclobutane

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2022
The formation and crystal structure of a zigzag molecular network held together by I...N halogen bonds is reported. In particular, the halogen-bond donor is 1,2-diiodoperchlorobenzene (1,2-C6I2Cl4) while the acceptor is a head-to-tail photoproduct ...
Taylor J. Dunning   +2 more
doaj   +1 more source

DNA photolyases of Chrysodeixis chalcites nucleopolyhedrovirus are targeted to the nucleus and interact with chromosomes and mitotic spindle structures [PDF]

open access: yes, 2010
Cyclobutane pyrimidine dimer (CPD) photolyases convert UV-induced CPDs in DNA into monomers using visible light as the energy source. Two phr genes encoding class II CPD photolyases PHR1 and PHR2 have been identified in Chrysodeixis chalcites ...
Xu, F. (Fang)   +12 more
core   +1 more source

Synthesis and structure of 2,4,6-tricyclobutyl-1,3,5-trioxane

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The synthesis and structure of 2,4,6,-tricyclobutyl-1,3,5-trioxane, C15H24O3 1, is described. It was formed in 39% yield during the work-up of the Swern oxidation of cyclobutylmethanol and may serve as a stable precursor of the cyclobutane carbaldehyde ...
Sergey V. Shorunov   +3 more
doaj   +1 more source

Controlling Topology within Halogen-Bonded Networks by Varying the Regiochemistry of the Cyclobutane-Based Nodes

open access: yesMolecules, 2021
The formation of a pair of extended networks sustained by halogen bonds based upon two regioisomers of a photoproduct, namely rctt-1,3-bis(4-pyridyl)-2,4-bis(phenyl)cyclobutane (ht-PP) and rctt-1,2-bis(4-pyridyl)-3,4-bis(phenyl)cyclobutane (hh-PP), that ...
Taylor J. Dunning   +3 more
doaj   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

open access: yesAngewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang   +1 more
wiley   +2 more sources

Microflow photochemistry: UVC-induced [2 + 2]-photoadditions to furanone in a microcapillary reactor

open access: yesBeilstein Journal of Organic Chemistry, 2013
[2 + 2]-Cycloadditions of cyclopentene and 2,3-dimethylbut-2-ene to furanone were investigated under continuous-flow conditions. Irradiations were conducted in a FEP-microcapillary module which was placed in a Rayonet chamber photoreactor equipped with ...
Sylvestre Bachollet   +5 more
doaj   +1 more source

Degradable Alternating Copolymers With Strained Cyclobutane Backbones via Photocontrolled RAFT Polymerization

open access: yesAngewandte Chemie, EarlyView.
A photocontrolled RAFT strategy enables the alternating copolymerization of 1,3‐disubstituted bicyclo[1.1.0]butanes with electron‐deficient comonomers, affording well‐defined copolymers bearing strained cyclobutane backbones. A high degree of alternation, tunable molecular weights, and excellent end‐group fidelity are achieved through a CTA‐mediated ...
Xia Hu   +4 more
wiley   +2 more sources

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