Syntheses of Isoxazoline-Based Amino Acids by Cycloaddition of Nitrile Oxides and Their Conversion into Highly Functionalized Bioactive Amino Acid Derivatives [PDF]
The present account illustrates the syntheses of isoxazoline- based amino acids by the cycloaddition of 1,3-dipolar nitrile oxides to the C–C double bond of unsaturated amino acid derivatives, with focus on the regio- and stereoselectivities of the ...
Fülöp, Ferenc +2 more
core
Stepwise [2 + 2] and [3 + 2] "cycloaddition" reactions of allenyl cations with olefins [PDF]
Halberstadt-Kausch, Inge K. +2 more
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Thiophene Derivatives as Versatile Precursors for (Hetero)Arene and Natural Product Synthesis
Hidden but Powerful: Thiophenes and their saturated analogues have been demonstrated to be versatile C4‐building blocks that can be rapidly applied to natural product synthesis and the construction of functionalized (hetero)arenes. This minireview aims to provide a concise overview of the strategies and implementations of these sulfur‐containing ...
Anna Keimer, Franz‐Lucas Haut
wiley +1 more source
Ring expansion of cyclobutylmethylcarbenium ions to cyclopentane or cyclopentene derivatives and metal-promoted analogous rearrangements [PDF]
D'hooghe, Matthias +2 more
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SYNTHESIS OF CYCLOBUTANE ANALOGUES
2-(3-Acetyl-2,2-dimethylcyclobutyl)acetic acid (pinonic acid) was synthesized using α-pinene as raw material and potassium permanganate as oxidant. This compound reacted with substituted aniline to produce eight kinds of derivatives with cyclobutane moiety. The yields of the cyclobutane analogues ranged from 24.9 to 78.2 %. KEY WORDS: Cyclobutane
Yan Bai Yin +4 more
openaire +2 more sources
2-(Aryl-sulfonyl)oxetanes as designer 3-dimensional fragments for fragment screening: synthesis and strategies for functionalisation. [PDF]
Bull, JA, Hollingsworth, IA, Morgan, KF
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Mapping the Undirected Borylation of C(sp3)-H Bonds in Strained Rings. [PDF]
La C +3 more
europepmc +1 more source
Synthetic Methods for Four-Membered Carbocycles Bearing Emerging Fluorinated Motifs. [PDF]
Yanai H +3 more
europepmc +1 more source
The configuration space of equilateral and equiangular hexagons [PDF]
Ohara, Jun
core +2 more sources

