Results 91 to 100 of about 2,936 (205)

A modular approach to prepare enantioenriched cyclobutanes: synthesis of (+)-rumphellaone A [PDF]

open access: yes, 2019
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features an 8-aminoquinolinamide directed C–H arylation reaction. The C–H arylation products were derivatized through subsequent decarboxylative coupling processes.
Beck, Jordan C.   +3 more
core  

The Thermal Decomposition of Cyclobutane [PDF]

open access: yesProceedings of the National Academy of Sciences, 1952
F, Kern, W D, Walters
openaire   +2 more sources

SYNTHESIS OF CYCLOBUTANE ANALOGUES

open access: yesBulletin of the Chemical Society of Ethiopia, 2009
2-(3-Acetyl-2,2-dimethylcyclobutyl)acetic acid (pinonic acid) was synthesized using α-pinene as raw material and potassium permanganate as oxidant. This compound reacted with substituted aniline to produce eight kinds of derivatives with cyclobutane moiety. The yields of the cyclobutane analogues ranged from 24.9 to 78.2 %. KEY WORDS: Cyclobutane
Yan Bai Yin   +4 more
openaire   +2 more sources

Efeito da sibutramina na redução do peso e no perfil metabólico em indivíduos obesos de uma população brasileira

open access: yesRevista de Ciências Farmacêuticas Básica e Aplicada, 2010
O objetivo deste trabalho é avaliar a eficácia e a segurança da dose de 20 mg/dia de sibutramina em voluntários obesos, com IMC superior a 35, e compará-las com a dose de 10 mg/dia e à mudança de estilo de vida de pacientes com IMC inferior a 35 (a ...
Carlos Alberto Menezes   +4 more
doaj  

Chemo- and Regioselective Synthesis of Alkynyl Cyclobutanes by Visible Light Photocatalysis

open access: yes, 2018
Here is the first visible light catalytic intermolecular cross [2 + 2] cycloaddition of enynes with alkenes to alkynyl cyclobutanes established with good functional group tolerance and high reaction efficiency and selectivity.
Tung, Chen-Ho   +23 more
core   +1 more source

Nuclear Magnetic Resonance Spectroscopy. Conformational Properties of Cyclobutanes. Variation of Geminal Fluorine—Fluorine Chemical-Shift Differences with Temperature

open access: yes, 1965
The temperature dependence of the geminal fluorine-fluorine chemical-shift differences in a variety of unsymmetrically substituted cyclobutanes is interpreted in terms of a classical equilibrium between axial and equatorial conformations.
Roberts, John D., Lambert, Joseph B.
core  

Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of (+)-Piperarborenine B

open access: yes, 2016
A highly diastereoselective and enantioselective Cu­(II)/SaBOX-catalyzed [2 + 2] cycloaddition of methylidenemalonate and multisubstituted alkenes was developed to furnish optically active cyclobutanes in high yields with >99/1 dr and up to >99% ee.
Yong Tang (161879)   +5 more
core   +1 more source

Cyclobutanes [PDF]

open access: yesChemical & Engineering News Archive, 2014
openaire   +1 more source

Tandem Au-Catalyzed 3,3-Rearrangement−[2 + 2] Cycloadditions of Propargylic Esters:  Expeditious Access to Highly Functionalized 2,3-Indoline-Fused Cyclobutanes

open access: yes, 2016
The treatment of readily available propargylic indole-3-acetates with a catalytic amount of AuCl(PPh3)/AgSbF6 leads to tandem activations of the propargylic esters and the in situ generated allenylic esters, resulting in expeditious access to highly ...
Liming Zhang (213971)
core   +1 more source

Palladium-Catalyzed Alkene Difunctionalization to Form Methylene Cyclobutanes, Methylene Cyclopentanes, and Tetrahydroberberines

open access: yes
Carbocycles and heterocycles are highly valuable synthetic building blocks, especially when they incorporate functional handles, such as amines. Palladium-catalyzed alkene difunctionalization is a mild and versatile method for the construction of these ...
Hatt, Jessica
core   +1 more source

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