Results 91 to 100 of about 1,032 (168)

The Thermal Decomposition of Cyclobutane [PDF]

open access: yesProceedings of the National Academy of Sciences, 1952
F, Kern, W D, Walters
openaire   +2 more sources

Catalytic asymmetric functionalization of bicyclo[1.1.0]butane boronic esters enabled by 1,2-oxygen migration

open access: yesNature Communications
The formation of boronate complexes through the coordination of alkoxide salts with organoborons serves as key intermediates in transition-metal-catalyzed coupling reactions.
Xin-Yuan Zhu   +3 more
doaj   +1 more source

A Modular Assembly of Amino Azetidines, Oxetanes, and Cyclobutanes

open access: yes
N-Boc azetidinone smoothly reacts with secondary amines and benzotriazole at room temperature to provide Katritzky benzotriazole adducts. The subsequent addition of Grignard reagents afforded amino azetidines.
Andrii Slobodianyk   +9 more
core   +1 more source

Overview of Photochemical Reactions for the Synthesis of Aza and Oxa‐Spirocyclic Compounds Under Visible Light Irradiation

open access: yesChemistry &Biodiversity, Volume 23, Issue 9, September 2026.
This review presents the visible‐light‐mediated photochemical reaction for the synthesis of aza, oxa, and aza–oxa spirocyclic compounds via photoinduced electron transfer (PET), hydrogen atom transfer (HAT), single‐electron transfer (SET), or energy transfer (EnT) pathways.
Annu Bhardwaj   +4 more
wiley   +1 more source

N‐Aryl Acridone Derivatives as Effective Catalysts for Energy Transfer Reactions

open access: yesChemistry – A European Journal, Volume 32, Issue 33, 1 September 2026.
Acridones derivatives have high triplet energy, are simple accessible, and could be used in challenging [2+2] ENT reactions. ABSTRACT Organic photocatalysts capable of promoting high‐energy triplet energy transfer (EnT) remain limited, particularly for demanding [2+2] photocycloaddition reactions.
Francesco Calogero   +8 more
wiley   +1 more source

A modular approach to prepare enantioenriched cyclobutanes: synthesis of (+)-rumphellaone A [PDF]

open access: yes, 2019
A modular synthesis of enantioenriched polyfunctionalized cyclobutanes was developed that features an 8-aminoquinolinamide directed C–H arylation reaction. The C–H arylation products were derivatized through subsequent decarboxylative coupling processes.
Beck, Jordan C.   +3 more
core  

A Physical Organic Odyssey: From the Ultrafast Dynamics of Carbenes and Nitrenes to Contemporary Chemical Biology and Drug Discovery

open access: yesJournal of Physical Organic Chemistry, Volume 39, Issue 9, September 2026.
Physical organic chemistry transforms photoaffinity labeling from empirical photochemistry into rational probe design. By measuring reactive‐intermediate lifetimes, pathways, and selectivity, Platz's legacy connects carbene and nitrene mechanisms to modern chemoproteomics, enabling more precise protein labeling and drug‐discovery maps.
Bin Yang, Jin Wang
wiley   +1 more source

RAD51 and RAD51 paralog inhibition sensitizes nonreplicating quiescent keratinocytes to UV radiation

open access: yesPhotochemistry and Photobiology, Volume 102, Issue 5, Page 1138-1149, September/October 2026.
UV radiation and other compounds generate DNA adducts that block transcription and induce cell death if not removed by the nucleotide excision repair system. In this work, we used a small‐scale pharmacological screen to discover that inhibition of the recombinase RAD51 sensitized nonreplicating quiescent keratinocytes to both UVR and other agents that ...
Saman Khan   +3 more
wiley   +1 more source

Natural Agents for Preventing Skin Damage Induced by Visible Light: A Systematic Review of Preclinical and Clinical Evidence

open access: yesPhotodermatology, Photoimmunology &Photomedicine, Volume 42, Issue 5, September 2026.
ABSTRACT Background/Purpose Visible light (VL), and particularly high‐energy visible light (HEVL), reaching Earth's surface has emerged as a relevant contributor to skin damage. VL has been implicated in oxidative stress, inflammation, pigmentation disorders, and photoaging, especially in individuals with darker skin phototypes.
Azahara Rodríguez‐Luna   +5 more
wiley   +1 more source

Efeito da sibutramina na redução do peso e no perfil metabólico em indivíduos obesos de uma população brasileira

open access: yesRevista de Ciências Farmacêuticas Básica e Aplicada, 2010
O objetivo deste trabalho é avaliar a eficácia e a segurança da dose de 20 mg/dia de sibutramina em voluntários obesos, com IMC superior a 35, e compará-las com a dose de 10 mg/dia e à mudança de estilo de vida de pacientes com IMC inferior a 35 (a ...
Carlos Alberto Menezes   +4 more
doaj  

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