[2]-Ladderanes as isosteres for meta-substituted aromatic rings and rigidified cyclohexanes [PDF]
Nature Communications, 2022 The development of new classes of isosteres and building blocks is crucial to the advancement of medicinal chemistry programs. Here, the authors report the synthesis and development of ladderanes to act as replacements for meta-substituted aromatic rings
Jay F Larrow +2 more
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A Theoretical Kinetic Study on Concerted Elimination Reaction Class of Peroxyl-hydroperoxyl-alkyl Radicals (•OOQOOH) in Normal-alkyl Cyclohexanes [PDF]
Molecules, 2023 The concerted elimination reaction class of peroxyl-hydroperoxyl alkyl radicals (•OOQOOH) plays a crucial role in the low-temperature combustion of normal-alkyl cyclohexanes.
Xiaoxia Yao, Jilong Zhang, Yifei Zhu
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Stereoselective intermolecular radical cascade reactions of tryptophans or ɤ-alkenyl-α-amino acids with acrylamides via photoredox catalysis [PDF]
Nature Communications, 2022 Photocatalytic radical cascade reactions enable the facile construction of diverse cyclic compounds, though they rely on templated precursors. In this paper, the authors report on stereoselective intermolecular radical cascade reaction between tryptophan
Jiang-Tao Li +5 more
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High-Pressure Limit and Pressure-Dependent Rate Rules for β-Scission Reaction Class of Hydroperoxyl Alkyl Hydroperoxyl Radicals (•P(OOH)2) in Normal-Alkyl Cyclohexanes Combustion [PDF]
MoleculesChemical kinetic studies of the β-scission reaction class of hydroperoxyl alkyl hydroperoxyl radicals (•P(OOH)2) from normal-alkyl cyclohexanes are carried out systematically through high-level ab initio calculations. Geometry optimizations and frequency
Xiaoxia Yao, Xiaoli Sun, Yifei Zhu
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Living supramolecular polymerization of fluorinated cyclohexanes
Nature Communications, 2021 Living supramolecular polymerization can produce precise covalent polymers, but the scope of monomers is still narrow. Here the authors show a molecular platform for living supramolecular polymerization that is based on the unique structure of all-cis 1 ...
Andrea Gardin +2 more
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Machine learning based estimation of density of binary blends of cyclohexanes in normal alkanes [PDF]
Scientific ReportsGiven the application of cycloalkanes in surrogate blends for aviation fuels, their determination of critical characteristics pertinent to fuel transportation and combustion becomes imperative.
Ali Yarahmadi, Ali Rashedi, Amin Bemani
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Synthesis of meta-carbonyl phenols and anilines [PDF]
Nature CommunicationsPhenols and anilines are of extreme importance for medicinal chemistry and material science. The development of efficient approaches to prepare both compounds has thus long been a vital research topic.
Bao-Yin Zhao, Qiong Jia, Yong-Qiang Wang
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Comprehensive Thermodynamic Study of Alkyl-Cyclohexanes as Liquid Organic Hydrogen Carriers Motifs
Hydrogen, 2023 Alkyl-cyclohexanes can be considered as suitable model compounds to understand the thermochemistry of aromatic compounds and their hydrogenated counterparts discussed as Liquid Organic Hydrogen Carrier systems.
Sergey P. Verevkin +4 more
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Molecules, 2020 Reaction of linear conjugated enynones, 1,5-diarylpent-2-en-4-yn-1-ones, with malononitrile in the presence of lithium diisopropylamide LDA, as a base, in THF at room temperature for 3–7 h resulted in the formation of the product of dimerization ...
Anastasiya V. Igushkina +4 more
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Novel Ring Systems: Spiro[Cycloalkane] Derivatives of Triazolo- and Tetrazolo-Pyridazines
Molecules, 2021 In orderto synthesize new pyridazine derivatives anellated with different nitrogen heterocyclic moieties, spiro[cycloalkane]pyridazinones were transformed into the corresponding thioxo derivatives via a reaction with phosphorus pentasulfide. The reaction
Csilla Sepsey Für +6 more
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