Diastereoselective synthesis of highly substituted cyclohexanones and tetrahydrochromene-4-ones via conjugate addition of curcumins to arylidenemalonates [PDF]
Beilstein Journal of Organic ChemistryA cascade inter–intramolecular double Michael strategy for the synthesis of highly functionalized cyclohexanones from curcumins and arylidenemalonates is reported. This strategy works in the presence of aqueous KOH using TBAB as a suitable phase transfer
Deepa Nair +3 more
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Ni-catalysed acceptorless dehydrogenative aromatisation of cyclohexanones enabled by concerted catalysis specific to supported nanoparticles [PDF]
Nature CommunicationsThe dehydrogenative aromatisation of cyclohexanone derivatives has had a transformative influence on the synthesis of aromatic compounds because functional groups can be easily introduced at desired positions via classic organic reactions without being ...
Takehiro Matsuyama +3 more
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MOF-808 as a Highly Active Catalyst for the Diastereoselective Reduction of Substituted Cyclohexanones [PDF]
Molecules, 2022 Zr-containing MOF-808 is an excellent heterogeneous catalyst for the diastereoselective Meerwein–Ponndorf–Verley reduction of substituted cyclohexanones.
Hans Hilmar Mautschke +1 more
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Correction: Diastereoselective synthesis of highly substituted cyclohexanones and tetrahydrochromene-4-ones via conjugate addition of curcumins to arylidenemalonates [PDF]
Beilstein Journal of Organic ChemistryDeepa Nair +4 more
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Reactions, 2022 A systematic study of the Diels–Alder reaction of α-nitrocinnamate was performed. The reaction of p-substituted α-nitrocinnamate with 2,3-dimethyl-1,3-butadienes smoothly proceeded regardless of the p-substituent, which was either an electron-donating or
Takumi Hamada +2 more
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Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity
Nature Communications, 2020 C-C bond scission of unstrained cycloketones with high regioselectivity is a challenging synthetic task. Here, the authors show a facile C-C cleavage of cyclohexanones and cyclopentanones with unusual selectivity under mild conditions with the aid of an ...
Mingyang Wang +5 more
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Influence of diluent alkyl substitution on the extraction of Am(III) and Eu(III) by a 6,6’-bis(1,2,4-triazin-3-yl)-2,2’-bipyridine ligand dissolved in alkylated cyclohexanone Diluents [PDF]
, 2012 Several alkylated cyclohexanones were investigated as potential diluents for the selective extraction of Am(III) from Eu(III) from nitric acid solutions by the CyMe4-BTBP ligand.
Distler, Petr +5 more
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Stereoselective (3+3)-Carbocyclization of Enamines with Nitroallylating Reagents
CHIMIA, 1985 The enamines from open-chain (3-pentanone) and cyclic (cyclopentanone, cyclohexanones, β-tetralone) ketones and the amines pyrrolidine, morpholine or (S)-2-methoxymethyl-pyrrolidine combine with E-3-phenyl-2-nitro-2-propen-1-yl or E-2-nitro-2-hepten-1 ...
Dieter Seebach +4 more
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A Highly Efficient Method for Synthesis of Bisarylmethylidenes of Cyclic Ketones in [BMIm]Cl/NaOH System as New and Recyclable Catalyst [PDF]
, 2014 An ionic liquid 1-Butyl-3-methylimidazoliumchloride[BMIm]Cl/sodium hydroxide system, was employed as a catalyst for the fast and one-pot crossed aldol-condensation of various aromatic aldehydes and cyclic ketones, to produce a variety of substituted α,α'-
Javad Eslami +2 more
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Beilstein Journal of Organic Chemistry, 2020 β-Nitrostyrenes underwent a Diels–Alder reaction with Danishefsky’s diene to afford cyclohexenes together with the corresponding hydrolyzed products, 3-arylated-5-methoxy-4-nitrocyclohexanones.
Haruyasu Asahara +2 more
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