Results 51 to 60 of about 19,839 (247)

Rational design of cyclopropane-based chiral PHOX ligands for intermolecular asymmetric Heck reaction

open access: yesBeilstein Journal of Organic Chemistry, 2014
A novel class of chiral phosphanyl-oxazoline (PHOX) ligands with a conformationally rigid cyclopropyl backbone was synthesized and tested in the intermolecular asymmetric Heck reaction.
Marina Rubina   +3 more
doaj   +1 more source

HIGH-RESOLUTION RAMAN SPECTROSCOPY OF GASES: XVIII. PURE ROTATIONAL SPECTRA OF CYCLOPROPANE AND CYCLOPROPANE-d6

open access: yes, 1964
A high-resolution study of the rotational Raman spectra of cyclopropane and cyclopropane-d6 has yielded the values 0.66962 ± 0.00020 cm−1 and 0.46079 ± 0.00015 cm−1 for their ground-state rotational constants.
W. Jeremy Jones, B. P. Stoicheff
core   +1 more source

Composés alicycliques à carbone quaternaire: IV. Phénomène de conjugaison chez les 1‐éthoxycarbonyl‐cyclopropane‐spiro‐cyclanes

open access: yes, 1956
Partant des alcoylidènecyclanes I à VIII, on a préparé les dérivés 1‐éthoxycarbonylés du cyclopropane‐spiro‐cyclobutane (IX), du cyclopropane‐spiro‐cyclopentane (X), du 2‐méthyl‐cyclopropane‐spiro‐cyclo‐pentane (XI), du cyclopropane‐spiro‐cyclohexane ...
Chiurdoglu, Grégoire   +5 more
core   +1 more source

Space-filling models of the cyclopropane molecule

open access: yes, 2022
   Cyclopropane is a cycloalkane, consisting of three methylene groups linked to each other to form a ring. The small size of the ring creates substantial ring strain in the structure. Cyclopropane itself is mainly of theoretical interest but many of its
Junjie Chen (13997541)
core   +1 more source

Synthese von Aminocyclopropanen durch redoxneutrale Aminoalkylierung

open access: yesAngewandte Chemie, EarlyView.
Wir berichten über eine Synthese von Aminocyclopropanen durch Hydroaminoalkylierung unter Einsatz kostengünstiger, leicht zugänglicher Ausgangsmaterialien. Der Ansatz bietet Orthogonalität zu gängigen Methoden und ermöglicht eine breite Toleranz gegenüber funktionellen Gruppen.
Gwyndaf A. Oliver   +6 more
wiley   +1 more source

HEAVY ATOM LARGE AMPLITUDE MOTION IN RG-CYCLOPROPANE COMPLEXES

open access: yes, 1997
Author Institution: Department of Chemistry, University of AlbertaRotation-tunneling spectra of the van der Waals Complex Ne-cyclopropane, and pure rotational spectra of Ar-cyclopropane and Kr-cyclopropane, were measured with a Fourier transform ...
Xu, Yunjie, Jäger, Wolfgang
core   +1 more source

Design, Synthesis, and Antimicrobial Activity of Amide Derivatives Containing Cyclopropane

open access: yesMolecules
As an important small organic molecule, cyclopropane is widely used in drug design. In this paper, fifty-three amide derivatives containing cyclopropane were designed and synthesized by introducing amide groups and aryl groups into cyclopropane through ...
Dongdong Chen   +5 more
doaj   +1 more source

Crystal structures of two bicyclo[5.1.0]octanes: potassium trans-bicyclo[5.1.0]octane-4-carboxylate monohydrate and cis-bicyclo[5.1.0]octan-4-yl 4-bromobenzenesulfonate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The crystal structures of the trans-fused compound potassium trans-bicyclo[5.1.0]octane-4-carboxylate monohydrate, K+·C9H13O2−·H2O, (I), and of cis-bicyclo[5.1.0]octan-4-yl 4-bromobenzenesulfonate, C14H17BrO3S, (II), have been determined.
Peter W. R. Corfield, Richard A. Kershaw
doaj   +1 more source

Synthesis of Chiral cis-Cyclopropane Bearing Indole and Chromone as Potential TNFα Inhibitors

open access: yes, 2018
Conformationally restricted analogues of SPD-304, the first small-molecule TNFα inhibitor, in which two heteroaryl groups, indole and chromone, are connected by chiral methyl- or ethyl-cis-cyclopropane, were designed.
Ryutaro Kanada (3364187)   +9 more
core   +1 more source

C-C Bond Lengths and Hybridization in some Cyclopropane Derivatives. GED Structure Studies of 1-Methyl-1-tert-butyl-cyclopropane and 1-Methyl-1-iso-propyl-cyclopropane [PDF]

open access: yes, 1991
The molecular structures of 1-methyl-1-tert-butyl-cyclopropane and 1- methyl-l-iso-propyl-cyclopropane have been studied by gas-phase electron diffraction.
Lüttke, Wolfgang   +1 more
core   +1 more source

Home - About - Disclaimer - Privacy