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Radical efficiency from azo-p-cymene
Tetrahedron, 1970Abstract The first-order rate constants (ki) and efficiencies of radical formation (e) for azo-p-cymene were measured in ten solvents spanning 80-fold in absolute viscosity and 30-fold in dielectric constant. Although viscosity plays a major role in the cage effect, specific solvation of p-cymyl radicals must also be considered. The ki exhibit little
W.F. Smith, K.L. Eddy
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Hydrogen abstraction from the isomeric cymenes
Tetrahedron, 1989Abstract The irradiation of cerium (IV) ammonium nitrate in the presence of ortho, meta and para cymene yields products from attack at the methyl group (the nitrates - these ones in 55 to 69% isolated yield-, the nitro derivatives, and the aldehydes) as well as at the isopropyl group (the acetophenones, not obtained from the ortho isomer), with ...
Sulpizio A +2 more
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Microbial transformation of p-cymene
2016More than 30 bacteria, fungi and yeast were evaluated for the biotransformation ability of p-cymene to obtain new metabolites. In the course of 14 days microbial biotransformation period, 16 different metabolites were detected by TLC and GC/MS methods.
Jivishov, Emil +3 more
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PARA-CYMENE STUDIES. III. THE BROMINATION OF 2-AMINO-PARA-CYMENE.
Journal of the American Chemical Society, 1921Alvin S. Wheeler, Ira W. Smithey
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Photochemical hydrogen abstraction from cymenes
The Journal of Organic Chemistry, 1989ALBINI, ANGELO, Sulpizio A.
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