Pd-catalyzed decarboxylative Heck vinylation of 2-nitrobenzoates in the presence of CuF2
Beilstein Journal of Organic Chemistry, 2010 A new protocol for the decarboxylative Heck vinylation of benzoic acids is disclosed. In the presence of a catalyst system generated in situ from Pd(OAc)2 (2 mol %), CuF2 (2 equiv), and benzoquinone (0.5 equiv) in NMP, a wide range of olefins were ...
Lukas J. Gooßen +2 more
doaj +1 more source
ECUT: Energy Conversion and utilization Technologies program biocatalysis research activity. Generation of chemical intermediates by catalytic oxidative decarboxylation of dilute organic acids [PDF]
A rhodium-based catalyst was prepared and preliminary experiments were completed where the catalyst appeared to decarboxylate dilute acids at concentrations of 1 to 10 vol%.
Distefano, S., Gupta, A., Ingham, J. D.
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A New Deacidification Strategy for Crude Vegetable Oil：Removal of Free Fatty Acids via Photobiocatalytic Decarboxylation [PDF]
, 2022 Xizhen Zhang +4 more
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Hydrothermal Decomposition of Amino Acids and Origins of Prebiotic Meteoritic Organic Compounds [PDF]
The organic compounds found in carbonaceous chondrite meteorites provide insight into primordial solar system chemistry. Evaluating the formation and decomposition mechanisms of meteoritic amino acids may aid our understanding of the origins of life and ...
Aponte, José C. +6 more
core +1 more source
Effects of Light Quantity and Quality on the Decarboxylation of Malic Acid in Crassulacean Acid Metabolism Photosynthesis [PDF]
, 1982 Simon R. Barrow, William Cockburn
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Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. [PDF]
, 2015 Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient ...
Jamison, Christopher R +4 more
core
C13 ISOTOPE EFFECT IN THE DECARBOXYLATION OF NORMAL MALONIC ACID [PDF]
, 1951 J. G. Lindsay, A. N. Bourns, H. G. Thode
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The conversion of L-histidine to glutamic acid by liver enzymes [PDF]
, 1952 Edlbacher and Neber (1) showed in 1934 that the liver enzyme named histidase degrades histidine to NH3, formic acid, and an unknown product which on further treatment with strong alkali yields glutamic acid.
Abrams, Adolph, Borsook, Henry
core
Asia-Pacific Journal of Chemical Engineering, EarlyView.ABSTRACT Carbon materials synthesized from biomass are promising candidates for supercapacitor electrodes. Various activation processes for developing carbon materials with high surface areas have been investigated. Here, a manganese monoxide (MnO)–porous‐activated carbon (AC) composite was fabricated via the chemical activation of coconut shell by the
Seung‐Heon Ryu +3 more
wiley +1 more source