Results 201 to 210 of about 111,262 (332)

β‐Amino Acid Synthesis Using the CO2 Radical Anion under Electrochemical and Photochemical Conditions

open access: yesChemistryEurope, EarlyView.
The development of sustainable methods for synthesizing β‐ and γ‐amino acids is crucial due to their significance in pharmaceuticals and materials science. This study introduces a novel strategy employing the CO2 radical anion as a key intermediate to access these amino acids from N‐Ac‐enamides and N‐Ac‐allylamines.
Tavinder Singh   +6 more
wiley   +1 more source

Nitrogen‐Centered Radical‐Directed C(sp3)−H Amination and Aminoalkylation Using (Diarylmethylene)amino Benziodoxolones

open access: yesChemistryEurope, EarlyView.
This report describes a C(sp3)−H aminofunctionalization via the photoexcitation of (diarylmethylene)amino benziodoxolones. These iodine reagents act as both single‐electron oxidants and nitrogen‐based SOMOphiles, serving as iminyl radicals, enabling the site‐selective C(sp3)−H amination and aminoalkylation of α‐aminoxy acid derivatives.
Kensuke Kiyokawa   +5 more
wiley   +1 more source

Photocatalytic Decarboxylative Functionalization of Bioactive, Naturally Occurring, and Fatty Acids Via Gem‐Borylsilyl Alkene

open access: yesChemistryEurope, EarlyView.
A photocatalytic, late‐stage decarboxylative functionalization of carboxylic acids using gem‐borylsilyl alkenes is described. This transformation enables the direct decarboxylative /radical addition of bioactive, naturally occurring, and fatty acids to gem‐B,Si alkenes, delivering synthetically valuable alkylboron,silayl under mild, visible‐light ...
Nadim Eghbarieh, Ahmad Masarwa
wiley   +1 more source

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