Results 81 to 90 of about 115,489 (367)

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

Advanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez, Alejandro Orellana‐Silla, Marta Galbiati, Efrén Navarro‐Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio‐Giménez, Sergio Tatay, Carlos Martí‐Gastaldo   +9 more
wiley   +1 more source

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

Angewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh, Nicole Hanania, Pinaki Nad, Tipu Alam, Tamir Kish, Ahmad Masarwa   +5 more
wiley   +2 more sources

Renewable Hydrocarbon Production from Waste Cottonseed Oil Pyrolysis and Catalytic Upgrading of Vapors with Mo-Co and Mo-Ni Catalysts Supported on γ-Al₂O₃

Nanomaterials, 2021
In this work, the production of renewable hydrocarbons was explored by the means of waste cottonseed oil (WCSO) micropyrolysis at 500 °C. Catalytic upgrading of the pyrolysis vapors was studied using α-Al2O3, γ-Al2O3, Mo-Co/γ-Al2O3, and Mo-Ni/γ-Al2O3 ...
Josué Alves Melo, Mirele Santana de Sá, Ainara Moral, Fernando Bimbela, Luis M. Gandía, Alberto Wisniewski   +5 more
doaj   +1 more source

Linked cycles of oxidative decarboxylation of glyoxylate as protometabolic analogs of the citric acid cycle

Nature Communications, 2018
The development of metabolic approaches towards understanding the origins of life, which have focused mainly on the citric acid (TCA) cycle, have languished—primarily due to a lack of experimentally demonstrable and sustainable cycle(s) of reactions.
G. Springsteen, J. Yerabolu, J. Nelson, Chandler Joel Rhea, R. Krishnamurthy   +4 more
semanticscholar   +1 more source

Synthesis of Polysubstituted Tetrahydro‐1,4‐Thiazepines by Rhodium‐Catalyzed Ring Expansion of Dihydro‐1,3‐Thiazines with Diazoesters

Advanced Synthesis &Catalysis, EarlyView.
A rhodium(II)‐catalyzed ring expansion of stereodefined dihydro‐1,3‐thiazines with diazomalonates gives 1,4‐thiazepines via a sulfonium ylide rearrangement. The reaction shows a cis/trans reactivity divergence arising from different metal coordination, as revealed by experiments and density functional theory studies.
Laurine Tual, Romain Pertschi, Gaëlle Blond, Mihaela Gulea   +3 more
wiley   +1 more source

Radical Electroprecipitation from a Water|Oil|Electrode Interface Prolongs “Electro”Chemiluminescence of the Tris(2,2′‐bipyridyl)Ruthenium(II) and Benzoyl Peroxide System by 103

Angewandte Chemie, EarlyView.
Multiphase systems, including ones with liquid‐liquid phase boundaries, are the home to many curious chemistries including reaction acceleration and spontaneous formation of reactive species. Here we show the liquid‐liquid interface causes electrochemiluminescence and afterglow chemiluminescence lifetime to be enhanced by 220,000% in‐time, far beyond ...
Daniel M. Carrel, Brady R. Layman, Megan L. Hill, Jeffrey E. Dick   +3 more
wiley   +2 more sources

Stereoelectronic Features of a Complex Ketene Dimerization Reaction

Molecules, 2021
The amidation reaction of a tetrahydroisoquinolin-1-one-4-carboxylic acid is a key step in the multi-kilogram-scale preparation of the antimalarial drug SJ733, now in phase 2 clinical trials. In the course of investigating THIQ carboxamidations, we found
Robert D. Barrows, Mark J. Dresel, Thomas J. Emge, Paul R. Rablen, Spencer Knapp   +4 more
doaj   +1 more source

Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis. [PDF]

, 2015
The coupling of tertiary carbon radicals with alkene acceptors is an underdeveloped strategy for uniting complex carbon fragments and forming new quaternary carbons.
Lackner, Gregory L, Overman, Larry E, Pratsch, Gerald, Quasdorf, Kyle W   +3 more
core   +3 more sources

ADA2 Forms Nuclear Condensates with GCN5 and ATP‐Citrate Lyase (ACL) to Modulate H3K9 Acetylation at Genes Functioning in Rice Meristems

Advanced Science, EarlyView.
This study unveils a novel GAA (GCN5‐ADA2‐ACL) complex that forms nuclear condensates to boost local acetyl‐CoA, facilitating histone acetylation and gene transcription in rice meristems. The research underscores the role of ADA2's disordered region in complex condensation and ACL's role in acetyl‐CoA production.
Yaping Yue, Tingting Lu, Xiaoyuan Guo, Biao Liu, Shiteng Lv, Heba A. M. Abdalla, Xuelei Lai, Ruihui Zhang, Jianpin Guo, Yu Zhao, Dao‐Xiu Zhou, Shaoli Zhou   +11 more
wiley   +1 more source

Photoinduced Ring‐Opening Polymerization of N‐Carboxyanhydrides for the Preparation of Cross‐Linked Polypeptide Gels

Angewandte Chemie, EarlyView.
We employ a photochemical approach for ring‐opening polymerization (ROP) of α‐amino acid N‐carboxyanhydride (NCA) monomers to prepare covalently cross‐linked synthetic polypeptide gels using a photobase and light, which offers significant advantages in the synthesis of polypeptides and holds great potential for applications requiring spatial and ...
Ana Kočman, David Pahovnik, Ema Žagar, Petra Utroša   +3 more
wiley   +2 more sources