Results 71 to 80 of about 4,540 (185)

Seasonal Restructuring of Microbial Communities and Resistomes in the Shitalakshya River, Bangladesh Revealed by Shotgun Metagenomics

open access: yesMicrobiologyOpen, Volume 15, Issue 4, August 2026.
Dry‐season pollutant concentration drives microbial restructuring in Bangladesh's Shitalakshya River, shifting communities from Myroides to stress‐tolerant genera while enriching metal resistance genes and efflux pumps, revealing non‐antibiotic co‐selection as a key driver of antimicrobial resistance in urban waters.
Muhammad Ehteshamul Haque   +3 more
wiley   +1 more source

Identification of Pyrazolidine‐3‐One Derivatives as a Novel Structural Scaffold for ATP Synthase Inhibitors

open access: yesChemMedChem, Volume 21, Issue 14, 29 July 2026.
Following the discovery of oxadiazin‐5‐ones as partial inhibitors of the ATP synthase, we herein report the synthesis of a library of pyrazolidine‐3‐ones and pyrazol‐3‐ones, designed by reducing the six‐membered N–N heterocycles to five‐membered rings.
Lisa Reichert   +8 more
wiley   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

open access: yesChemistry – A European Journal, Volume 32, Issue 28, 25 July 2026.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome   +6 more
wiley   +1 more source

Evaluation of Iron‐Phosphate Glass–Ceramic Waste Form for Electrorefiner Salt Waste Simulant Dechlorinated With Phosphoric Acid

open access: yesInternational Journal of Ceramic Engineering & Science
The importance of glass and glass–ceramic nuclear waste forms has been reaffirmed in recent years by the growing interest in nuclear power as a reliable energy source.
Harmony Werth   +6 more
doaj   +1 more source

Cobamide-mediated enzymatic reductive dehalogenation via long-range electron transfer

open access: yesNature Communications, 2017
Cobalamin-containing reductive dehalogenases from organohalide-respiring bacteria play a key role in the degradation of halogenated organic compounds. Here the authors proposed a catalytic mechanism for dehalogenation that relies on a long-range electron
Cindy Kunze   +6 more
doaj   +1 more source

Abiotic reductive dehalogenation of pharmaceuticals with naturally occurring redox mediators

open access: yesEnvironmental Advances
This preliminary study investigated whether a reductive dehalogenation of brominated, chlorinated and fluorinated pharmaceuticals is possible using redox mediators as found for iodinated x-ray contrast media.
Kerstin Gerundt   +2 more
doaj   +1 more source

Co7-cluster metal–organic frameworks for photocatalytic dehalogenation reduction

open access: yesPolyoxometalates
Photocatalytic dehalogenation reduction, which converts a C–X bond into a C–H bond, plays a significant role in synthetic catalysis and pollutant remediation.
Sumeng Liu   +6 more
doaj   +1 more source

Engineered halohydrin dehalogenase mediates remote enantiocontrolled dehalogenative hydroxylation via an unconventional mechanism

open access: yesNature Communications
Expanding enzyme catalytic diversity is essential to unlocking the full potential of biocatalysis for green chemistry. Halohydrin dehalogenases are promiscuous biocatalysts that typically mediate the intramolecular dehalogenative cyclization of ...
Xiao Jin   +6 more
doaj   +1 more source

Electrochemical Hydrodehalogenation Based on 3D‐Printed Electrodes

open access: yesChemElectroChem
Additive manufacturing has emerged as a versatile platform for electrode fabrication, offering cost efficiency, design flexibility, and compatibility with a wide range of materials.
Jennifer Christina Schmidt, Dandan Gao
doaj   +1 more source

(Ph3P)4C4P4: Effect of substitution on the Oligomerization of carbon phosphide radicals

open access: yesChemistryEurope
Dehalogenation of (PBr)2C2(PPh3)2 with potassium graphite, KC8, leads to Cs‐P4C4(PPh3)4, which can be viewed as a PPh3 adduct of a Cs‐symmetric P4C4 cage.
Dr. Moritz Scharnhölz   +5 more
doaj   +1 more source

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