Results 71 to 80 of about 7,561 (225)

Activation of Aryl Halides by Triplet–Triplet Annihilation Upconversion Enabling Coupling Processes Under an Open‐to‐Air Environment

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Triplet–triplet annihilation upconversion (TTA‐UC) performed inside supramolecular viscoelastic gels enables efficient CC and C–heteroatom coupling reactions under green LED irradiation in open‐air conditions. The gel network restricts oxygen diffusion, preserves triplet states, and allows aryl halide activation through upconverted excited states ...
Daniel Álvarez‐Gutiérrez   +4 more
wiley   +1 more source

Energy-harvesting bio-electro-dehalogenation for sustainable wastewater treatment

open access: yes, 2018
The concept of an “energy-harvesting bio-electro-dehalogenation” process is demonstrated, where exoelectrogenic bacteria in an anodic chamber of a microbial fuel cell (MFC) are used to capture and exploit the electrical energy stored in the biodegradable
Hansen, Hans Christian B.   +6 more
core   +1 more source

Photochemical Dehalogenation of Aryl Halides: Importance of Halogen Bonding

open access: yes, 2019
Upon UVA irradiation, aryl halides can undergo dehalogenation in the presence of bases and methanol as a hydrogen donor. This catalyst-free photochemical dehalogenation is furnished through a facile radical chain reaction under mild conditions. The chain
Costa P.   +4 more
core   +3 more sources

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

The Reductive Dehalogenation of Chloroethenes, Dichlorophenol, and Chlorobenzenes

open access: yes, 2008
The improper disposal of chlorinated compounds has become an environmental concern and its remediation is a priority. Dehalococcoides ethenogenes strain 195 is able to reductively dehalogenate tetrachloroethene (PCE), trichloroethene (TCE) and 2,3 ...
Fung, Jennifer
core  

Mechanisms of bacterially catalyzed reductive dehalogenation.

open access: yes, 1992
Nine bacteria were tested for the ability to dehalogenate tetrachloromethane (CT), tetrachloroethene (PCE), and 1,1,1-trichloroethane (TCA) under anaerobic conditions. Three bacteria were able to reductively dehalogenate CT.
Picardal, Flynn William
core   +1 more source

Regioselective alkali metal reduction of dibenzocyclooctadiene lignan derivatives, demethoxylation followed by dehalogenation

open access: yesChemistry Central Journal, 2017
The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system.
Qing-yao Wang   +4 more
doaj   +1 more source

Visible‐light‐promoted catalyst‐free benzylic C‐H oxidation using molecular oxygen as a green oxidant

open access: yesSmart Molecules, EarlyView.
A green and simple photo‐oxygenation of benzylic C‐H bond with molecular oxygen was developed for the preparation of a series of carbonyl compounds. The straightforward C‐H carbonylation strategy features catalyst‐ and additive‐free reaction conditions, only oxygen as a green oxidant, broad scope and scalable, and the simple‐operation nature.
Jianing Li   +6 more
wiley   +1 more source

Pure Water-Induced Dehalogenation of 2,4-Di-tert-amino-6-substituted-5-halogenopyrimidines

open access: yes, 2018
Dehalogenation of 5-halogenopyrimidine derivatives in boiling pure water was accomplished in high yields. The substrate and pure water are the only two reaction components in this process.
Mahsa Mousavi (5019053)   +3 more
core   +1 more source

Heterogeneous Iodine Chemistry Impacts Reactive Halogen and Oxidant Abundances

open access: yesGeophysical Research Letters, Volume 53, Issue 11, 16 June 2026.
Abstract Tropospheric reactive halogens influence the oxidizing capacity of the atmosphere. Although previous studies have shown that iodine exerts the strongest impact on tropospheric ozone concentrations compared to chlorine and bromine, the impact of aerosol iodide recycling back to the gas phase on oxidants has not been estimated prior to this work.
Allison R. Moon   +22 more
wiley   +1 more source

Home - About - Disclaimer - Privacy