Facile Access to N‐Substituted Pyridyl Ligands
A modular, robust, and versatile Buchwald–Hartwig amination protocol that enables the rapid synthesis of bipyridine, phenanthroline, terpyridine, and pybox ligands bearing dialkylamine, diarylamine, and heteroaromatic N‐substituents. Pyridyl motifs equipped with N‐substituents can be powerful ligands for catalysis, yet their broader adoption is limited
Adam Petrik +5 more
wiley +1 more source
Modeling the observed tropospheric BrO background: Importance of multiphase chemistry and implications for ozone, OH, and mercury [PDF]
Aircraft and satellite observations indicate the presence of ppt (ppt ≡ pmol/mol) levels of BrO in the free troposphere with important implications for the tropospheric budgets of ozone, OH, and mercury.
Dix, Barbara +13 more
core +2 more sources
Experimental High‐Throughput Electrochemistry
This review highlights experimental high‐throughput electrochemistry as a powerful approach to accelerate electrochemical research. Key technologies such as automated platforms, microelectrode arrays, and machine learning‐based optimization are discussed, with a focus on applications in electrocatalysis, battery research, and electrosynthesis ...
Jens Noack
wiley +1 more source
Learning from B12 enzymes: biomimetic and bioinspired catalysts for eco-friendly organic synthesis
Cobalamins (B12) play various important roles in vivo. Most B12-dependent enzymes are divided into three main subfamilies: adenosylcobalamin-dependent isomerases, methylcobalamin-dependent methyltransferases, and dehalogenases. Mimicking these B12 enzyme
Keishiro Tahara +3 more
doaj +1 more source
Bicyclic chloro-, bromo- and iodo-γ-lactones with dimethylcyclohexane rings were used as substrates for bioconversion by several fungal strains (<em>Fusarium</em>, <em>Botrytis</em> and <em>Beauveria</em>). Most of the
Małgorzata Grabarczyk
doaj +1 more source
Generation of a Ground‐State Electron Donor Utilizing Stored Light Energy
Chemically stored light energy enables the generation of dianion reductants (∼−2.7 V) from vicinal diols derived from diaryl ketone photodimerization. These ground‐state electron donors efficiently reduce challenging substrates at room temperature, including aryl bromides, alkyl iodides, and sulfonamides.
Marc Taillefer +2 more
wiley +1 more source
Identifying the Burdens and Opportunities for Tribes and Communities in Federal Facility Cleanup Activities: Environmental Remediation Technology Assessment Matrix For Tribal and Community Decision-Makers [PDF]
The cleanup of this country's federal facilities can affect a wide range of tribal and community interests and concerns. The technologies now in use, or being proposed by the Department of Energy, Department of Defense and other federal agencies can ...
Jeanne M. Rubin +2 more
core
Bacterial diversity and reductive dehalogenase redundancy in a 1,2-dichloroethane-degrading bacterial consortium enriched from a contaminated aquifer [PDF]
Background Bacteria possess a reservoir of metabolic functionalities ready to be exploited for multiple purposes. The use of microorganisms to clean up xenobiotics from polluted ecosystems (e.g.
Massimo Marzorati +7 more
core +3 more sources
Background The side reactions of dehalogenation or C–N coupling tend to occur when halogenated aromatic amines are prepared by catalytic hydrogenation reduction of halogenated aromatic nitro compounds.
Haichang Guo +4 more
doaj +1 more source
Synthesis and application of zeolite and glass fiber supported zero valent iron nanoparticles as membrane component for removal nitrate and Cr (+6) ions [PDF]
In the present paper the synthesis and characterization of zeolite and glass fiber supported zero valent iron nanoparticles (Ze-ZVI, GF-ZVI NPs) are reported.ZVI, Ze-ZVI and GF-ZVI NPs size, composition and morphology were characterized by Scanning ...
Allahverdiyeva, Gunel R. +4 more
core +1 more source

