Results 81 to 90 of about 15,936 (220)
Chemoenzymatic Synthesis of Triazololactams Structurally Related to Pancratistatin [PDF]
Four tricyclic lactams that structurally resemble alkaloids with the pancratistatin skeleton were synthetized from bromobenzene by a chemoenzymatic strategy.
Bastida +48 more
core +1 more source
This work investigates the formation of high‐alkali‐iron‐phosphate glass–ceramic waste forms made from the dechlorinated product of a phosphoric acid‐based process. The salt simulant is mixed with H3PO4 to form a slurry, heated, and then the dechlorinated product is vitrified with glass formers to obtain the final waste form. ABSTRACT The importance of
Harmony Werth +6 more
wiley +1 more source
The regioselective demethoxylation and dehalogenation of dihalogenated dibenzocyclooctadiene lignans derivatives were realized in a one-step reaction with excellent yields in the sodium and t-butanol reaction system.
Qing-yao Wang +4 more
doaj +1 more source
A pH Dependant Switch in DHP Oxidation Mechanism [PDF]
Dehaloperoxidase (DHP) is a multifunctional enzyme found in Amphitrite ornata, a sediment-dwelling marine worm. This enzyme possess the structure of a traditional hemoglobin enzyme and serves as the primary oxygen carrier in A.
Fehr, Travis
core +1 more source
Highly active iridium(I) complexes for the selective hydrogenation of carbon-carbon multiple bonds [PDF]
New iridium(I) complexes, bearing a bulky NHC/phosphine ligand combination, have been established as extremely efficient hydrogenation catalysts that can be used at low catalyst loadings, and are compatible with functional groups which are often ...
Andersson, Shalini +5 more
core +1 more source
Intercepting 1,2‐Diamantene: A Doubly Bridgehead Anti‐Bredt Alkene
Doubly bridgehead olefin 1,2‐diamantene, which resembles an elusive trans‐cyclohexene moiety was generated from 1,2‐diiododiamantane. The diamantane scaffold thermodynamically and kinetically stabilizes this highly twisted olefin due to efficient hyperconjugation with the C–C bonds of the cage, while dimerization is hampered due to steric crowding ...
Andrey A. Fokin +2 more
wiley +1 more source
Radiation damage in sub‐Ångström resolution macromolecular crystallography: a low‐dose study
This first systematic radiation‐damage study at 0.55 Å resolution reveals extensive small conformational changes in response to dose. The findings demonstrate the benefits of using large crystals fully bathed in a large `top‐hat' beam with a uniform fluence profile, together with low‐dose data‐collection protocols, for sub‐Ångström structure ...
Gleb Bourenkov +7 more
wiley +1 more source
In the environment, bacteria sense aromatic pollutants, migrate toward them, adapt to toxicity, and deploy specialized uptake and catabolic systems. Genomic plasticity, metabolic versatility and division of labor within populations together aid in the degradation of persistent aromatics, highlights that biodegradation is driven by various eco ...
Prashant S. Phale +2 more
wiley +1 more source
Trastuzumab is an antibody used for the treatment of human epidermal growth factor receptor 2 (HER2)-overexpressing breast cancers. Since trastuzumab is an internalizing antibody, two factors could play an important role in achieving high uptake and ...
Satish K. Chitneni +3 more
doaj +1 more source
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda +5 more
wiley +1 more source

