Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh +2 more
wiley +1 more source
Diastereoselective synthesis of cyclopropyl sulfoxides <i>via</i> hydrosulfenation. [PDF]
Yuwen L +6 more
europepmc +1 more source
A Low‐Symmetry FeII Tetrahedron From a Flexible Tritopic Ligand
A highly symmetric and flexible tris‐bidentate tritopic ligand forms an S4 meso homoleptic face‐capped FeII tetrahedron near‐quantitatively in acetonitrile. The addition of nitromethane solvent causes partial isomerization of this meso cage to the racemic homochiral tetrahedron, with the complexity of the system being moderated through solvophobic ...
Rosemary J. Goodwin +5 more
wiley +1 more source
Further elaboration of the stereodivergent approach to chaetominine-type alkaloids: synthesis of the reported structures of aspera chaetominines A and B and revised structure of aspera chaetominine B. [PDF]
Lü JF, Wu JF, Ye JL, Huang PQ.
europepmc +1 more source
Formal nitrogen-to-carbon replacement in isoindolines to form indenes <i>via N</i>-alkyl tetrahydroisoquinolines. [PDF]
Steele RT, Domack J, Sarpong R.
europepmc +1 more source
Dihydroquercetin in Obesity and Prediabetes: Case Report and Insights from Molecular Modeling. [PDF]
Terekhov RP +8 more
europepmc +1 more source
Synthesis of depressin, cryptomeridiol and 4-<i>epi</i>-cryptomeridiol enabled by a terpenoid chiral pool-producing platform. [PDF]
Kong Y +8 more
europepmc +1 more source
The Formose Reaction with SO<sub>2</sub>: A Computational Study. [PDF]
Sisson EM, Kua J.
europepmc +1 more source
Fluorohydrin Synthesis via Formal C-H Fluorination of Cyclic Alcohols. [PDF]
Edens HMJ, West JG.
europepmc +1 more source
Analytical Challenges in Detecting New Psychoactive Substances in Anti-Doping: A Proof-of-Concept Involving Pentedrone Metabolite. [PDF]
Kwiatkowska D +8 more
europepmc +1 more source

