Base-catalyzed diastereoselective trimerization of trifluoroacetone
Anthony P. Silvestri, Philip E. Dawson
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Highly chemo-, enantio-, and diastereoselective [4 + 2] cycloaddition of 5H-thiazol-4-ones with N-itaconimides [PDF]
Shuai Qiu +2 more
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Catalytic, Diastereoselective 1,2-Difluorination of Alkenes.
S. Banik, J. Medley, E. Jacobsen
semanticscholar +1 more source
Asymmetric total synthesis of tricyclic prostaglandin D2 metabolite methyl ester via oxidative radical cyclization. [PDF]
Xiao M, Pu L, Shang Q, Zhu L, Huang J.
europepmc +1 more source
Diastereoselective Synthesis of the Pectenotoxin 2 Non-Anomeric AB Spiroacetal
Danielle Vellucci, Scott D. Rychnovsky
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The power of catalytic promiscuity: The enantioselective conjugate hydrocyanation of enals remains a long‐standing challenge for biocatalysis. Here, we report the redesign of 2‐deoxy‐D‐ribose‐5‐phosphate aldolase for the asymmetric conjugate hydrocyanation of aromatic enals, expanding the reaction scope of iminium‐based enzyme catalysis to include an ...
Hangyu Zhou +3 more
wiley +1 more source
Correction: Diastereoselective synthesis of highly substituted cyclohexanones and tetrahydrochromene-4-ones via conjugate addition of curcumins to arylidenemalonates. [PDF]
Nair D +4 more
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Titanium‐Catalyzed Intermolecular Hydrothiomethylation of Alkenes
Hermetically sealable, inexpensive 42‐well aluminum reactor blocks are used to explore new reactivities of air‐ and moisture‐sensitive titanium catalysts. As a result, methyl sulfides undergo efficient α‐alkylation with alkenes in the presence of a titanium catalyst precursor, a formamidinato ligand, and a Lewis acid, yielding branched ...
Hermann Thye +3 more
wiley +1 more source
Application of Asymmetric Catalysis in the <i>E</i>/<i>Z</i>-Stereodivergent Synthesis of Alkenes. [PDF]
Liu M, Kanale VV, Uyeda C.
europepmc +1 more source

