Results 221 to 230 of about 83,038 (344)
Asymmetric, Organocatalytic 1,4-Addition of Pyridinyl Acetates with Crystallization-Enabled Diastereoconvergency. [PDF]
Kitzinger KM +3 more
europepmc +1 more source
Diastereoselective sulfur ylide rearrangements from gold catalyzed oxidation of ynamides
Joshua D. Priest +2 more
openalex +2 more sources
C3‐Symmetric aluminum chelate complexes endowed with tripodal tris‐silanolate ligands are shown to be excellent catalysts for the selective carbonyl ene‐type cyclization of citronellal to isopulegol as the key intermediate of the current industrial syntheses of menthol.
J. Nepomuk Korber, Alois Fürstner
wiley +1 more source
Asymmetric Synthesis of the Pentacyclic Framework of <i>Kopsia</i> Alkaloids. [PDF]
Song Y, Park J, Kim S.
europepmc +1 more source
A set of fourteen well‐defined rhodium and iridium complexes containing various enantiopure cyclic(alkyl)(amino)carbene (ChiCAAC) ligands (>96% ee to > 99.5% ee) has been synthesized and fully characterized. While no enantioselectivity is observed with chiral Rh‐CAAC, the Ir‐CAAC counterparts demonstrated good performances in the asymmetric ...
Fanny Morvan +7 more
wiley +1 more source
Advances in the Total Synthesis of Angular Triquinane-Type Natural Products. [PDF]
Wang X, Liu D, Cheng Y.
europepmc +1 more source
Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes.
Richard Y. Liu, Yang Yang, S. Buchwald
semanticscholar +1 more source
Copper‐Catalyzed Defluorinative Allylboration of Allenes with Trifluoromethyl Alkenes
A copper‐catalyzed borylative coupling of allenes with 1‐trifluoromethyl alkenes is reported. The reaction selectively provides synthetically versatile borylated 1,1‐difluoro‐1,5‐dienes that can be converted into a range of medicinally relevant fluorinated compounds. Mechanistic studies reveal a key role of the catalytically generated LiCl by assisting
Martín Piñeiro‐Suárez +3 more
wiley +1 more source

