Results 81 to 90 of about 19,176 (260)

Effect of Reaction Media on Photosensitized [2+2]‐Cycloaddition of Cinnamates

open access: yesChemistryOpen, 2020
The outcome of photosensitized [2+2]‐cycloaddition reactions of various cinnamates has been compared in different reaction media, including homogeneous organic solutions under inert conditions, degassed water, and aerated physical gels.
Alex Abramov   +2 more
doaj   +1 more source

Intra- and Intermolecular Diastereoselectivity of 5-Hydroxy-2-adamantylidene†

open access: yes, 2016
Intra- and Intermolecular Diastereoselectivity of 5-Hydroxy-2-adamantylidene†
Udo H. Brinker (1470559)   +1 more
core   +1 more source

Monovalent chiral-at-copper complexes: halide-controlled diastereoselectivity [PDF]

open access: yes, 2012
An unusual example of diastereoselectivity has been observed in Cu(κ3-P,C,P′-1)X complexes where 1 is an asymmetric tridentate ligand containing a bicyclic NHC framework and X is a halide.
Newman, Paul David   +2 more
core   +1 more source

Synthesis of Substituted Oxo-Azepines by Regio- and Diastereoselective Hydroxylation

open access: yesMolecules, 2017
Substituted seven-membered N-heterocycles are prevalent bioactive epitopes and useful synthons for preparing enzyme inhibitors or molecular recognition systems.
Harold Spedding, Peter Karuso, Fei Liu
doaj   +1 more source

diastereoselectivity

open access: yes
Citation: 'diastereoselectivity' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08162 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for
openaire   +1 more source

Diastereoselective Transfer Hydrogenation of Cyclic and Bicyclic Ketones over Selected Metal Oxides as Catalysts

open access: yesMolecules
The diastereoselectivity of the liquid- and vapor-phase Catalytic Transfer Hydrogenation (CTH) of cyclic ketones: x-methylcyclohexanones (x = 2, 3 or 4), 4-t-butylcyclohexanone, and bicyclic ketones: 2-norbornanone, camphor, fenchone, and a tricyclic ...
Marek Gliński   +6 more
doaj   +1 more source

Synthesis of 3-substituted isoxazolidin-4-ols using hydroboration–oxidation reactions of 4,5-unsubstituted 2,3-dihydroisoxazoles

open access: yesBeilstein Journal of Organic Chemistry, 2020
Isoxazolidines represent a very important class of N/O-containing heterocycles used as the key intermediates in the synthesis of more complex cyclic and acyclic compounds, including various biologically active molecules.
Lívia Dikošová   +3 more
doaj   +1 more source

Facile Chemical Access to Biologically Active Norcantharidin Derivatives from Biomass

open access: yesMolecules, 2017
Reductive amination of 2,5-diformylfuran (DFF) was used to implement the transition from bio-derived 5-hydroxymethylfurfural (HMF) to pharmaceuticals.
Konstantin I. Galkin   +5 more
doaj   +1 more source

Additions to Fe(CO)3−Dienal Complexes:  Dependence of Diastereoselectivity on Lewis Acid

open access: yes, 2016
Lewis acid mediated additions to Fe(CO)3−2,4-dienal complexes are explored. Silyl enol ether and allylstannane nucleophiles both undergo aldehyde addition with good diastereoselectivity.
Daniel F. Harvey (3031866)   +1 more
core   +1 more source

Fusicoccin Ring System by [4 + 4] Cycloaddition. Control of Diastereoselectivity through Hydrogen Bonding

open access: yes, 2016
Fusicoccin Ring System by [4 + 4] Cycloaddition.
Scott McN. Sieburth (1538176)   +2 more
core   +1 more source

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