Self‐Immolative Poly(Benzyl Ether)s: Design Principles and Controlled Depolymerization
Unzipping to Sustainability: This Concept article explores the thermodynamic design of quinone‐methide (QM)‐based poly(benzyl ether)s (PBEs). It explains how a low ceiling temperature (Tc), QM stability, and an entropic gain drive rapid depolymerization (“unzipping”) of PBEs into monomers.
Ji Woo Kim, Yewon Kang, Hyungwoo Kim
wiley +1 more source
Spiroketal Synthesis Via Uncatalyzed Inverse Electron-Demand Hetero-Diels-Alder Reactions at Ambient Temperature. [PDF]
Greene EJ +5 more
europepmc +1 more source
Asymmetric Access to Structurally Complex 1-Tetralols through Diels-Alder Cycloadditions of Photogenerated Hydroxy-o-quinodimethanes and Acrylates. [PDF]
González-Marcos M +5 more
europepmc +1 more source
“Smelltronics”—From Gas to Smell Sensing
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono +7 more
wiley +1 more source
Thermoreversible Diels-Alder Crosslinked Networks in Recycled Poly(ethylene terephthalate) for Reprocessability and Self-Healing. [PDF]
Liu Y +6 more
europepmc +1 more source
The Elements of Chiral Brønsted Acids for Stereoselective Transformations
This review focuses on chiral Brønsted acids (CBAs), examining how each structural component influences the stereochemical outcome. For each element—scaffold, acidic site, substituents—we identify advantages and disadvantages relevant to the catalyst design and selection.
Diego A. Cruz‐Aguilar +3 more
wiley +1 more source
Stable Vicinal Bisketene Equivalents for Aryne Diels-Alder Reactions. [PDF]
Budwitz JE, Newton CG.
europepmc +1 more source
Endophytic fungi encode abundant cryptic biosynthetic gene clusters that remain largely silent under conventional cultivation. This review highlights how genome mining, multi‐omics, and cluster activation strategies bridge the BGC‐to‐metabolite gap, enabling the discovery of structurally diverse antibacterial natural products with activity against ...
Farkhod Eshboev +8 more
wiley +1 more source
Synthesis of Spiro-Bridged 3,4-Dihydrocoumarins Through an Organocatalytic Cascade Sequence Diels-Alder/Nucleophilic Ring Closing. [PDF]
Medina-Ortíz A +4 more
europepmc +1 more source
Diels–Alder reactions in the preparation of furan materials
Luonnonvarojen rajallisuus on nostanut kysyntää kestävästi valmistettaville sekä käyttöiältään parempien materiaalien valmistukselle. Eräs lähestymistapa tähän kysyntään vastaamiseksi on lignoselluloosasta jalostettavan furaanin termoreversiibelin Diels ...
Haapasalo, Tuukka
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