Unusual Structure-Energy Correlations in Intramolecular Diels–Alder Reaction Transition States [PDF]
Molecules, 2014 Detailed analysis of calculated data from an experimental/computational study of intramolecular furan Diels–Alder reactions has led to the unusual discovery that the mean contraction of the newly forming C-C σ-bonds from the transition state to the ...
Justyna M. Żurek +3 more
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C(alkyl)–C(vinyl) bond cleavage enabled by Retro-Pallada-Diels-Alder reaction [PDF]
Nature Communications, 2023 Activation and cleavage of carbon–carbon (C–C) bonds is a fundamental transformation in organic chemistry while inert C–C bonds cleavage remains a long-standing challenge.
Qingyang Zhao +6 more
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A Simple Entry to the 5,8-Disubstituted Indolizidine Skeleton via Hetero Diels-Alder Reaction [PDF]
Molecules, 2023 The 5,8-disubstituted indolizidines are the largest family of indolizidines isolated from the skin of amphibians. These compounds exhibit interesting biological activities such as noncompetitive blockers of nicotinic receptors.
Juan Francisco Rodríguez-Caro +2 more
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New tandem Ugi/intramolecular Diels–Alder reaction based on vinylfuran and 1,3-butadienylfuran derivatives [PDF]
Beilstein Journal of Organic ChemistryA new tandem sequence involving the Ugi reaction and Diels–Alder [4 + 2] cycloaddition based on vinylfuran and 1,3-butadienylfuran derivatives was designed and studied.
Yuriy I. Horak +5 more
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Thermally Induced Intramolecular Diels–Alder Reaction of Furan-Tethered Methylenecyclopropanes [PDF]
MoleculesThe substantial ring strain and activated double bonds render methylenecyclopropanes (MCPs) potential substrates for Diels–Alder (DA) reactions. In this work, we present a thermally induced intramolecular Diels–Alder (IMDA) reaction utilizing furan ...
Qi-Yun Huang +3 more
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Progress in Lewis-Acid-Templated Diels–Alder Reactions [PDF]
MoleculesThe synthesis of natural products with complicated architectures often requires the use of segments with functional groups that can be structurally transformed with the desired stereogenic centers.
Jun Ishihara
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Cerium(III) immobilized on the functionalized halloysite as a highly efficient catalyst for aza-Diels-Alder reaction. [PDF]
Sci RepHosseini A +4 more
europepmc +3 more sources
Synthesis of benzoquinone compounds by a microdroplet-accelerated retro-Diels-Alder reaction. [PDF]
Chem SciMalkoti N, Meng Y, Zare RN, Gnanamani E.
europepmc +3 more sources
Dual-locked targeted alpha-emitter enhanced tumor immunotherapy via Diels-Alder reaction-based self-immolative molecular cage strategy. [PDF]
Mil Med ResYang MD +10 more
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Inverse-Electron-Demand Diels-Alder Reaction of Tropone with Graphene Supported on Cu(111). [PDF]
SmallTu J, Zhou W, Wolf LM, Yan M.
europepmc +3 more sources