Hetero Diels-Alder Cycloaddition of Siloxy Vinylallenes-Synthesis of the Indolizidine Skeleton: Experimental and Computational Studies. [PDF]
Rodríguez-Caro JF +3 more
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The Expanding Role of Diazirines in Synthetic Methodology
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic +3 more
wiley +1 more source
Diels-Alder reaction affords circumpyrene tetracarboxydiimide with excited state intramolecular charge transfer character. [PDF]
Chen Q +10 more
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A modular farnesyltransferase‐based chemoenzymatic platform enables fast, site‐specific labeling of nanobodies for PET imaging of inflammation. CD11b‐targeted PET agents selectively image myeloid‐driven inflammation, while CD45‐targeted PET agents provide sensitive whole‐body immune mapping.
Sneha Venkatachalapathy +7 more
wiley +1 more source
NMR-Based Structural Analysis of Highly Substituted Pyridines From Kondrat'eva Aza-Diels-Alder Cycloadditions. [PDF]
Suárez-Moreno GV +6 more
europepmc +1 more source
Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +1 more source
A Comprehensive View on the Molecular Mechanism of the Diels-Alder Reaction Between 2,3-Dimethylbutadiene and E-2-Phenyl-1-Nitroethene: CDFT/ELF, <sup>14</sup>C Kinetic Isotope Effects, Electron Density Transfers, Reaction Profiles and BET Analyses. [PDF]
Woliński P, Łącka W, Jasiński R.
europepmc +1 more source
Achiral benzoic acid appended helical polymers for the copper-catalyzed asymmetric Diels-Alder reaction and Michael addition with excellent enantioselectivity and recyclability. [PDF]
Ti QH, Mo MY, Gao RT, Liu N, Wu ZQ.
europepmc +1 more source
Magnetic Induction Heating Enables On-Demand Drug Release via Diels-Alder Polymeric Nanocarriers. [PDF]
Fujisawa N, Ebara M, Lai JJ.
europepmc +1 more source

