Site-selective bromination of anthracene-maleimide Diels-Alder crystals for tunable afterglow and white light emission. [PDF]
Yang G +5 more
europepmc +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Asymmetric Total Synthesis of C2-OH Lycopodium Alkaloids (-)-Palhinine B, (-)-Palhinine C, and (+)-Palhinine B Enabled by Stereocontrolled Diels-Alder Strategy. [PDF]
Pantawane A +6 more
europepmc +1 more source
Emergent Atropisomerism Through Diels–Alder Reactions of Vinylallenes
Cycloaddition‐induced geometric reorganization transforms achiral vinylallenes into atropisomeric styrenes. Conformational flexibility governs atropisomerization barriers, thermodynamic preferences, and configurational stability. Atropisomeric styrenes remain comparatively underdeveloped because configurational stability about the C(sp2)C(sp2) bond is
Kusum Sai +3 more
wiley +1 more source
The elusive <i>endo</i>-product of the archetypal Diels-Alder reaction of furan and maleic anhydride - observed in the solid state at last. [PDF]
Lennox CB +10 more
europepmc +1 more source
Diels-Alder Click Chemistry as a Dynamic-Covalent Crosslinking Method in Spheroid-Encapsulating Hydrogels for Cartilage Engineering. [PDF]
van de Looij SM +8 more
europepmc +1 more source
Diels-Alder Reactions in [Pd<sub>6</sub>L<sub>4</sub>]<sup>12+</sup> Metallocages: The Key Roles of Preorganization and Confinement. [PDF]
Sciortino G +3 more
europepmc +1 more source
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua +3 more
wiley +1 more source
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik +11 more
wiley +1 more source
Sulfonyl-Directed Photoinduced Dehydro-Diels-Alder Reaction of Aryl Maleimides: Enabling Regioselective Naphthalene Synthesis. [PDF]
Song XH +5 more
europepmc +1 more source

