Results 21 to 30 of about 81,226 (245)

Design, fabrication and characterization of dynamic covalent polymer networks containing reversible Diels-Alder adducts derived from vegetable oil and furfural

open access: yesPolymer Testing, 2023
The exploration of novel bio-based functional polymers has high application value and confirms to sustainable development strategies following the increasing shortage of fossil resources.
Yuan Nie   +9 more
doaj   +1 more source

The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings

open access: yesPolímeros, 2005
The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character.
Alessandro Gandini
doaj   +1 more source

Applications of Danishefsky's dienes in asymmetric Oxo-Diels-Alder reactions

open access: yes, 2022
Applications of Danishefsky's dienes in catalytic asymmetric hetero-Diels-Alder (AHDA) reactions or specifically, their asymmetric Oxo-Diels-Alder (AOxo-DA) reactions with appropriate dienophiles are highlighted in detail, including the preparation of
AfsanehTaheri kal Koshvandi (11996987)   +1 more
core   +1 more source

Synthesis and Spectrophotometric Analysis of 1-Azafluorenone Derivatives

open access: yesMolecules, 2020
A new extension for the ‘one pot’ construction of diverse 1-azafluorene derivatives featuring a Diels–Alder/retro-Diels–Alder cycloaddition is reported. Conditions were also determined for oxidation to the derived azafluorenones.
Nicholas H. Angello   +3 more
doaj   +1 more source

Generation of novel Diels–Alder reactions using a generative adversarial network [PDF]

open access: yes, 2022
Deep learning has enormous potential in the chemical and pharmaceutical fields, and generative adversarial networks (GANs) in particular have exhibited remarkable performance in the field of molecular generation as generative models.
Yejian, Wu   +14 more
core   +2 more sources

A broadly applicable Diels-Alder based Synthesis of Ketamine related Arylcyclohexylamines [PDF]

open access: yes, 2022
Herein we report the synthesis of both aryl derivatives of ketamine and aryl derivatives of ketamine’s major metabolites hydroxynorketamine (HNK), norketamine (NK) and dehydronorketamine (DHNK) via a microwave-assisted Diels-Alder reaction to form the ...
Sherif, El Sheikh   +3 more
core   +2 more sources

Niobium Pentachloride Activation of Enone Derivatives: Diels-Alder and Conjugate Addition Products

open access: yesMolecules, 2002
Niobium pentachloride has proven to be a powerful activating agent for Diels-Alder or conjugate addition reactions of cycloenones. The Diels-Alder product was obtained only with an unsubstituted enone (cyclohexenone) and the highly reactive diene ...
Gil Valdo José da Silva   +2 more
doaj   +1 more source

An Asymmetric Synthetic Approach to the A-ring of the Taxol Family of Anti-Cancer Compounds

open access: yesMolecules, 1998
A synthetic route developed for the preparation of the A-ring of Taxol family of molecules is reported. By means of an intramolecular Diels-Alder reaction an asymmetric approach to this ring has been accomplished.
M. L. Marin, D. Craig
doaj   +1 more source

Diels-Alder Additions to 2,2’-Biaceanthrylene [PDF]

open access: yes, 2021
A series of Diels-Alder reactions between the diene 2,2’-biaceanthylene and several dienophiles is presented. The diene is a cyclopenta-fused polycyclic aromatic hydrocarbon with anthracene units linked by two cyclopentene rings.
Kyle, Plunkett, Yachu, Du
core   +2 more sources

Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction

open access: yesMolecules, 2007
The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst.
Kyle E. Litz
doaj   +1 more source

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