Results 31 to 40 of about 77,395 (287)

Masked Bisketenes as Diels–Alder Dienes [PDF]

open access: yes, 2020
2,5-Bis(tert-butyldimethylsilyloxy)furans are established as masked vicinal bisketenes for application as dienes in the Diels–Alder reaction.
Emma, Becroft   +4 more
core   +2 more sources

Diels-Alder Additions to 2,2’-Biaceanthrylene [PDF]

open access: yes, 2021
A series of Diels-Alder reactions between the diene 2,2’-biaceanthylene and several dienophiles is presented. The diene is a cyclopenta-fused polycyclic aromatic hydrocarbon with anthracene units linked by two cyclopentene rings.
Kyle, Plunkett, Yachu, Du
core   +2 more sources

Tandem Diels—Alder/Ene Reactions. [PDF]

open access: yesChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Kraus, George, Kim, Junwon
openaire   +3 more sources

An Asymmetric Synthetic Approach to the A-ring of the Taxol Family of Anti-Cancer Compounds

open access: yesMolecules, 1998
A synthetic route developed for the preparation of the A-ring of Taxol family of molecules is reported. By means of an intramolecular Diels-Alder reaction an asymmetric approach to this ring has been accomplished.
M. L. Marin, D. Craig
doaj   +1 more source

Screening of chiral Diels-Alder catalysts by mass spectrometric monitoring of the retro reaction [PDF]

open access: yes, 2007
A rapid screening procedure for the identification of chiral Diels-Alder catalysts by ESI MS was developed. Screening of the retro reaction made it possible to indirectly determine the catalyst’s enantioselectivity for the forward, product-forming ...
Teichert, Antje Maria
core   +1 more source

Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction

open access: yesMolecules, 2007
The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst.
Kyle E. Litz
doaj   +1 more source

Oxidative [4+2] annulation of styrenes with alkynes under external-oxidant-free conditions

open access: yesNature Communications, 2018
A sequence of a Diels–Alder reaction and oxidation is a powerful route to valuable aromatic compounds. Here, the authors report a more atom-economical oxidant-free strategy involving a Diels–Alder with H2 evolution under noble-metal-free photoredox ...
Guoting Zhang   +5 more
doaj   +1 more source

A broadly applicable Diels-Alder based Synthesis of Ketamine related Arylcyclohexylamines [PDF]

open access: yes, 2022
Herein we report the synthesis of both aryl derivatives of ketamine and aryl derivatives of ketamine’s major metabolites hydroxynorketamine (HNK), norketamine (NK) and dehydronorketamine (DHNK) via a microwave-assisted Diels-Alder reaction to form the ...
Sherif, El Sheikh   +3 more
core   +2 more sources

Theoretical study on the Diels-Alder reaction of bromo-substituted 2H-pyrane-2-ones and some substituent vinyls [PDF]

open access: yesJournal of the Serbian Chemical Society, 2015
A DFT study of the reactivity, regio- and stereoselectivity of Diels-Alder reaction between 3-bromo, 5-bromo, and 3,5-dibromo-2(H)-pyran-2-ones and some weakly activated and unactivated alkenes has been carried out using density functional ...
Haghdadi Mina, Amani Hamed, Nab Nasim
doaj   +1 more source

Electrostatic catalysis of a Diels–Alder reaction [PDF]

open access: yesNature, 2016
It is often thought that the ability to control reaction rates with an applied electrical potential gradient is unique to redox systems. However, recent theoretical studies suggest that oriented electric fields could affect the outcomes of a range of chemical reactions, regardless of whether a redox system is involved.
Aragonès, A.   +7 more
openaire   +5 more sources

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