Results 51 to 60 of about 375 (147)

A tribute to Professor Dr Kai A. I. Zhang: pioneering advances in metal‐free polymeric photocatalysis

open access: yesPolymer International, Volume 75, Issue 1, Page 34-43, January 2026.
Polymeric photocatalysts have emerged as metal‐free materials with tunable structures. This review highlights the contributions of Professor Dr Kai A. I. Zhang in advancing polymer‐based photocatalysts. Abstract Polymeric photocatalysts have emerged as promising alternatives to traditional metal‐based catalysts due to their tunable properties, low cost
Bolormaa Bayarkhuu   +2 more
wiley   +1 more source

Visible-light induced photocatalyst-free difluoromethylation of quinoxalinones with difluorosulfones

open access: yesGreen Synthesis and Catalysis
Visible-light induced direct C–H difluoromethylation of quinoxalinones with 2-((difluoromethyl)sulfonyl)benzo[d]thiazole has been developed for the first time.
Linlin Shi   +6 more
doaj   +1 more source

Carbonylative Transformations of Aryl Sulfonium Salts

open access: yesChemistry–Methods, Volume 5, Issue 12, November 2025.
Carbonyl derivatives are widely present in biologically active molecules, pharmaceuticals, natural products, and materials, and their synthesis has garnered much attention. Direct carbonylation of aromatic CH bonds is an effective tool for the synthesis of carbonyl compounds.
Yan‐Hua Zhao, Xiao‐Feng Wu
wiley   +1 more source

Recent Advances in Stereospecific Transformations of Organoboron Reagents

open access: yesTransformative Chemistry, Volume 1, Issue 1, December 2025.
Enantioenriched boronic esters when activated with organolithiums, can be transformed into boronate complexes that act as chiral organometallic‐type nucleophiles and can engage a wide variety of electrophiles in stereospecific cross‐coupling reactions.
Shubham Ojha   +3 more
wiley   +1 more source

Photoredox‐Catalyzed Synthesis of a Novel Class of Fluoroalkyl Pyrazolones

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 21, November 13, 2025.
A photoredox strategy enables regioselective synthesis of fluoroalkyl 2‐pyrazolin‐5‐ones via radical addition and cyclization. This mild, metal‐free method shows a broad substrate scope, operates in batch and flow systems, and offers a sustainable approach to fluorinated heterocycles with potential applications in medicinal chemistry.
Emanuele F. Pissinati   +3 more
wiley   +1 more source

Electrosynthesis of 1,1-Bis(difluoromethyl)alkenes via Twofold C−H Difluoromethylation as Bioisosteres of Elusive 1,1-Enediols

open access: yesNature Communications
Geminal bis(difluoromethyl)alkenes, featuring two CF2H groups as lipophilic hydrogen-bond donor surrogates, are highly coveted yet rarely accessible bioisosteres of 1,1-enediols that remain nearly theoretical due to their inherent instability.
Seonyoung Kim   +5 more
doaj   +1 more source

O-Difluoromethylation of 1,3-diones with S-difluoromethyl sulfonium salt

open access: yesRSC Advances, 2016
S-Difluoromethyl sulfonium salt was found to be a difluorocarbene precursor and direct difluoromethylation reagent in the O-difluoromethylation of 1,3-diones.
Chun-Bo Yue   +6 more
openaire   +1 more source

Effect of 7-Difluoromethyl-5, 4΄-dimethoxygenistein on aorta atherosclerosis in hyperlipidemia ApoE-/- mice induced by a cholesterol-rich diet

open access: yesDrug Design, Development and Therapy, 2013
Yong Zhang,1,2 Lesai Li,3 Jiliang You,2 Jianguo Cao,2 Xiaohua Fu2 1Department of Hematology, Xiangya Hospital, Central South University, Changsha, People's Republic of China; 2College of Medicine, Hunan Normal University, Changsha, People's ...
Zhang Y, Li L, You J, Cao J, Fu X
doaj  

Direct C-H difluoromethylation of heteroaromatic compounds: emerging methods and developments through 2025. [PDF]

open access: yesRSC Adv
Hossaini Z   +8 more
europepmc   +1 more source

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