Results 81 to 90 of about 1,271 (129)
9-(4-Formylphenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione
In the title compound, C24H26O4, the central 4H-pyran ring adopts a flattened boat conformation, with the mean and maximum deviations of the ring being 0.0582 (6) and 0.1012 (3) Å, respectively.
R. Kalaivanan +2 more
doaj +1 more source
The kinetics of oxidation of dimedone in perchloric acid medium were studied spectrophotometrically. The reaction showed first order kinetics in quinolinium dichromate (QDC) concentration and an order of less than unity in 5,5-dimethylcyclohexane-1,3 ...
Sharanappa T. Nandibewoor +2 more
core +1 more source
Glutathione-based products, GSnX, of the reaction of hydrogen sulfide, H2S, S-nitroso glutathione, and GSNO, at varied stoichiometries have been analyzed by liquid chromatography high-resolution mass spectrometry (LC-HRMS) and chemical trapping ...
Murugaeson R Kumar, Patrick J Farmer
doaj +1 more source
Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety [PDF]
A series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes.
Maryam Robati +3 more
doaj
The structure of Dimedone and the effect of solvents on Keto-enol Tautomerism
An infra-red spectroscopic examination of dimedone has shown that in non-polar solvents this compound exists in the diketo- rather than the mono-en01 form.
CL Angell, RL Werner
core +1 more source
Aqueous citric acid as green reaction media for the synthesis of octahydroxanthenes
A simple, convenient and environmentally friendly one-pot procedure for the synthesis of 1,8-dioxo-octahydroxanthenes by the reaction of dimedone and aromatic aldehydes in aqueous citric acid is described. In this green synthetic protocol promoted by the
Camilo A. Navarro D. +2 more
doaj
A queer product of the Beirut reaction with dimedone-AM1 analysis
Dimedone reacted with benzofuraxane in the presence of Et3N. The expected products were quinoxaline derivatives but an unexpected compound was obtained in low yield. The structural identification of the product was done spectrally and a mechanism for its
Dura, E, Türker, Burhan Lemi
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The preparation of dimedone derivatives of amino acids and their use in peptide synthesis
The preparation of dimedone derivatives of amino acids has been effected by saponification of the corresponding alkyl esters, and also by catalytic hydrogenation of the respective benzyl esters.
B Halpern
core +1 more source
Reaction of 5,5-dimethylcyclohexane-1,3-dione (dimedone), aldehydes and cyanogen bromide in the presence of triethylamine leads to the selective formation of spiro dihydrofurans in moderate to good yields at room ...
Pesyan, Nader Noroozi +3 more
core +1 more source
[Fe(III)(Salen)Cl] Complex as a Catalyst for the Synthesis of 1, 8-Dioxo-Octahydroxanthene Derivatives [PDF]
1, 8-Dioxo-octahydroxanthene derivatives have efficiently been synthesized from dimedone and aromatic aldehydes using [Fe(III)(salen)Cl] complex as an efficient and homogeneous catalyst in molten tetrabutyl ammonium bromide.
H. Khabazzadeh +2 more
doaj

