Results 81 to 90 of about 1,271 (129)

9-(4-Formylphenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione

open access: yesIUCrData, 2018
In the title compound, C24H26O4, the central 4H-pyran ring adopts a flattened boat conformation, with the mean and maximum deviations of the ring being 0.0582 (6) and 0.1012 (3) Å, respectively.
R. Kalaivanan   +2 more
doaj   +1 more source

Spectral and Mechanistic Investigations of the Oxidative Transformation of 5,5-Dimethylc Yclohexane-1,3 -Dione (Dimedone) by Quinolinium Dichromate in Perchloric Acid Medium

open access: yes, 2010
The kinetics of oxidation of dimedone in perchloric acid medium were studied spectrophotometrically. The reaction showed first order kinetics in quinolinium dichromate (QDC) concentration and an order of less than unity in 5,5-dimethylcyclohexane-1,3 ...
Sharanappa T. Nandibewoor   +2 more
core   +1 more source

Characterization of Polysulfides, Polysulfanes, and Other Unique Species in the Reaction between GSNO and H2S

open access: yesMolecules, 2019
Glutathione-based products, GSnX, of the reaction of hydrogen sulfide, H2S, S-nitroso glutathione, and GSNO, at varied stoichiometries have been analyzed by liquid chromatography high-resolution mass spectrometry (LC-HRMS) and chemical trapping ...
Murugaeson R Kumar, Patrick J Farmer
doaj   +1 more source

Synthesis of new 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone moiety containing 4-thiazolidinone moiety [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2017
A series of novel 1, 8-dioxo-octahydroxanthene derivatives containing 4-thiazolidinone framework (4a-f) were synthesized through a four-step reaction starting from the reduction of nitro derivatives of 1, 8-dioxo-octahydroxanthenes.
Maryam Robati   +3 more
doaj  

The structure of Dimedone and the effect of solvents on Keto-enol Tautomerism

open access: yes, 1953
An infra-red spectroscopic examination of dimedone has shown that in non-polar solvents this compound exists in the diketo- rather than the mono-en01 form.
CL Angell, RL Werner
core   +1 more source

Aqueous citric acid as green reaction media for the synthesis of octahydroxanthenes

open access: yesRevista Colombiana de Química, 2013
A simple, convenient and environmentally friendly one-pot procedure for the synthesis of 1,8-dioxo-octahydroxanthenes by the reaction of dimedone and aromatic aldehydes in aqueous citric acid is described. In this green synthetic protocol promoted by the
Camilo A. Navarro D.   +2 more
doaj  

A queer product of the Beirut reaction with dimedone-AM1 analysis

open access: yes, 2002
Dimedone reacted with benzofuraxane in the presence of Et3N. The expected products were quinoxaline derivatives but an unexpected compound was obtained in low yield. The structural identification of the product was done spectrally and a mechanism for its
Dura, E, Türker, Burhan Lemi
core   +1 more source

The preparation of dimedone derivatives of amino acids and their use in peptide synthesis

open access: yes, 1965
The preparation of dimedone derivatives of amino acids has been effected by saponification of the corresponding alkyl esters, and also by catalytic hydrogenation of the respective benzyl esters.
B Halpern
core   +1 more source

Selective formation of spiro dihydrofurans from one-pot reaction of dimedone with BrCN and aldehydes in the presence of Et3N

open access: yes, 2013
Reaction of 5,5-dimethylcyclohexane-1,3-dione (dimedone), aldehydes and cyanogen bromide in the presence of triethylamine leads to the selective formation of spiro dihydrofurans in moderate to good yields at room ...
Pesyan, Nader Noroozi   +3 more
core   +1 more source

[Fe(III)(Salen)Cl] Complex as a Catalyst for the Synthesis of 1, 8-Dioxo-Octahydroxanthene Derivatives [PDF]

open access: yesJournal of Sciences, Islamic Republic of Iran, 2013
1, 8-Dioxo-octahydroxanthene derivatives have efficiently been synthesized from dimedone and aromatic aldehydes using [Fe(III)(salen)Cl] complex as an efficient and homogeneous catalyst in molten tetrabutyl ammonium bromide.
H. Khabazzadeh   +2 more
doaj  

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