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This work presents a clinically deployable simultaneous PET/MRI workflow which integrates hyperpolarized 13C imaging of metabolism and extracellular pH with [18F]FMISO PET to characterize hypoxia, acidosis, and metabolic reprogramming in feline sarcoma.
Martin Grashei +17 more
wiley +1 more source
Bioactive phenylboronic acid–chitosan nanoparticles enable responsive silymarin delivery for post‐hepatectomy liver protection. The nanoplatform integrates antioxidant and antibacterial functions, improves hepatic recovery, and is associated with coordinated shifts in gut microbiota, metabolites, cytokines, and hepatic proteomic pathways, suggesting a ...
Jinjin Tong +9 more
wiley +1 more source
A rational, solvent‐free synthesis utilizing 2,6‐diaminonaphthalene produces ultrabright green‐emissive carbon dots. Regulated by a self‐limiting oxidative capping mechanism, excitons undergo ultrafast intra‐particle funneling from the nitrogen‐doped carbon core to emissive surface traps.
Hyeonjin Park +8 more
wiley +1 more source
Optimization of supercritical dimethyl carbonate method for biodiesel production [PDF]
Biodiesel could be produced from triglycerides and dimethyl carbonate, instead of the conventional methanol, in this non-catalytic supercritical dimethyl carbonate method.
Zul Ilham, Shiro Saka
exaly +2 more sources
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The Chemistry of Dimethyl Carbonate
Accounts of Chemical Research, 2002Dimethyl carbonate (DMC) is a versatile compound that represents an attractive eco-friendly alternative to both methyl halides (or dimethyl sulfate) and phosgene for methylation and carbonylation processes, respectively. In fact, the reactivity of DMC is tunable: at T = 90 degrees C, methoxycarbonylations take place, whereas at higher reaction ...
TUNDO, Pietro, SELVA, Maurizio
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Photolysis of dimethyl carbonate
Transactions of the Faraday Society, 1966The gas-phase photolysis of dimethyl carbonate (DMC) has been studied in the temperature range 41–93°C. Methoxyl and methyl radicals are generated in this photolysis and their reactions have been studied. Arrhenius parameters have been measured for the following reactions: [graphic omitted] A value of 1014.13(mole–1 cm3 sec–1) at 41°C has been ...
M. J. Yee Quee, J. C. J. Thynne
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Thermodynamic Properties of Dimethyl Carbonate
Journal of Physical and Chemical Reference Data, 2011A thermodynamic property formulation for dimethyl carbonate has been developed with the use of available experimental thermodynamic property data. The equation of state was developed with multiproperty fitting methods involving pressure-density-temperature (pρT), heat capacity, vapor pressure, and saturated-liquid density data.
Yong Zhou, Jiangtao Wu, Eric W. Lemmon
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Review on the synthesis of dimethyl carbonate
Catalysis Today, 2018Abstract Dimethyl carbonate (DMC, (CH3O)2CO), as an important and environmentally friendly chemical intermediate, has been widely used in industrial fields. Several large-scale industrial routes of DMC production, e.g., phosgene route, transesterification route, and the liquid-phase oxidative carbonylation of methanol, have been developed to date ...
Hong-Zi Tan +7 more
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Dimethyl carbonate as a green chemical
Current Opinion in Green and Sustainable Chemistry, 2017Dimethyl carbonate (DMC) is an established solvent and a green reagent which continues to attract attention. It is a nonpolar aprotic solvent with good miscibility with water, biodegrades readily in the atmosphere, and is non-toxic. DMC is classified in the greenest “recommended” bracket according to the solvent selection guide, and can be a potential ...
Sang-Hyun Pyo +3 more
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On the conformational behavior of dimethyl carbonate
Physical Chemistry Chemical Physics, 1999Infrared (4000–50 cm-1) spectra of the vapor, the amorphous and crystalline solid phase, and Raman spectra (4000–50 cm-1) of the vapor, liquid and crystalline solid phases of dimethyl carbonate have been recorded, and assignments are proposed. MP2 and DFT abinitio calculations were carried out using a 6-31G** basis set.
Bohets, H., van der Veken, B.J.
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