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Dimethyl carbonate as potential reactant in non-catalytic biodiesel production by supercritical method [PDF]
In this study, the non-catalytic supercritical method has been studied in utilizing dimethyl carbonate. It was demonstrated that, the supercritical dimethyl carbonate process without any catalysts applied, converted triglycerides to fatty acid methyl ...
Zul Ilham, Shiro Saka
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Photolysis of dimethyl carbonate
Transactions of the Faraday Society, 1966The gas-phase photolysis of dimethyl carbonate (DMC) has been studied in the temperature range 41–93°C. Methoxyl and methyl radicals are generated in this photolysis and their reactions have been studied. Arrhenius parameters have been measured for the following reactions: [graphic omitted] A value of 1014.13(mole–1 cm3 sec–1) at 41°C has been ...
M. J. Yee Quee, J. C. J. Thynne
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Dimethyl carbonate as a green chemical
Current Opinion in Green and Sustainable Chemistry, 2017Dimethyl carbonate (DMC) is an established solvent and a green reagent which continues to attract attention. It is a nonpolar aprotic solvent with good miscibility with water, biodegrades readily in the atmosphere, and is non-toxic. DMC is classified in the greenest “recommended” bracket according to the solvent selection guide, and can be a potential ...
Sang-Hyun Pyo +3 more
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Review on the synthesis of dimethyl carbonate
Catalysis Today, 2018Abstract Dimethyl carbonate (DMC, (CH3O)2CO), as an important and environmentally friendly chemical intermediate, has been widely used in industrial fields. Several large-scale industrial routes of DMC production, e.g., phosgene route, transesterification route, and the liquid-phase oxidative carbonylation of methanol, have been developed to date ...
Hong-Zi Tan +7 more
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Thermodynamic Properties of Dimethyl Carbonate
Journal of Physical and Chemical Reference Data, 2011A thermodynamic property formulation for dimethyl carbonate has been developed with the use of available experimental thermodynamic property data. The equation of state was developed with multiproperty fitting methods involving pressure-density-temperature (pρT), heat capacity, vapor pressure, and saturated-liquid density data.
Yong Zhou, Jiangtao Wu, Eric W. Lemmon
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Reaction Chemistry & Engineering, 2021
Ultrasound can accelerate the reaction rate of alcoholysis of ethylene carbonate and improve the reaction efficiency.
Yueyue He +3 more
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Ultrasound can accelerate the reaction rate of alcoholysis of ethylene carbonate and improve the reaction efficiency.
Yueyue He +3 more
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SYNTHESIS OF DEUTERATED DIMETHYL CARBONATE
Canadian Journal of Chemistry, 1956not available
R. Renaud, L. C. Leitch
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Dimethyl Carbonate as a Green Reagent
ChemInform, 2007AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Pietro Tundo, Maurizio Selva
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Journal of Molecular Liquids, 2015
Abstract Phase diagrams of lithium salt systems in dimethyl sulfoxide, propylene carbonate and dimethyl carbonate have been obtained and conductivity measurements have been performed in the concentration range up to 0.25 mole fraction of a salt. The shape of the phase diagrams has been analyzed thermodynamically and the following order of anions for ...
S.A. Kirillov +4 more
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Abstract Phase diagrams of lithium salt systems in dimethyl sulfoxide, propylene carbonate and dimethyl carbonate have been obtained and conductivity measurements have been performed in the concentration range up to 0.25 mole fraction of a salt. The shape of the phase diagrams has been analyzed thermodynamically and the following order of anions for ...
S.A. Kirillov +4 more
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Synthesis of Fluorinated Dimethyl Carbonates by Direct Fluorination
Synthetic Communications, 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
Masahiro Takehara +4 more
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