Results 21 to 30 of about 3,577 (190)

Intramolecular Cycloaddition of Imines of Cysteine Derivatives

open access: yesMolecules, 1998
Azomethine ylides were generated from Schiffs bases of S-allylcysteine methyl ester and their intramolecular 1,3-dipolar cycloadditions were studied. These reactions led to the synthesis of thieno[3,4-b]pyrrole derivatives in good yield.
Teresa M. V. D. Pinho e Melo   +2 more
doaj   +1 more source

1,3-Dipolar Cycloaddition Reactions of Azomethine Ylides with Carbonyl Dipolarophiles Yielding Oxazolidine Derivatives

open access: yesMolecules, 2016
We provide a comprehensive account of the 1,3-dipolar cycloaddition reactions of azomethine ylides with carbonyl dipolarophiles. Many different azomethine ylides have been studied, including stabilized and non-stabilized ylides.
Adam G. Meyer, John H. Ryan
doaj   +1 more source

A study on selective transformation of norbornadiene into fluorinated cyclopentane-fused isoxazolines

open access: yesBeilstein Journal of Organic Chemistry, 2021
This work presents an examination of the selective functionalization of norbornadiene through nitrile oxide 1,3-dipolar cycloaddition/ring-opening metathesis (ROM)/cross-metathesis (CM) protocols. Functionalization of commercially available norbornadiene
Zsanett Benke   +2 more
doaj   +1 more source

Asymmetric 1,3-Dipolar Cycloadditions to 5-Menthyloxy-2[5H]-furanones. [PDF]

open access: yes, 1988
Cycloadditions of various 1,3-dipolar reagents to chiral butenolides 1 and 5 proceed with diastereomeric excess of 20-100%.
Lange, Ben de,   +5 more
core   +1 more source

Arylthio-substituierte Nitrilylide aus der Thermolyse von 4-Arylthio-3-oxazolin-5-onen

open access: yesCHIMIA, 1984
Thermolysis of 4-arylthio- and 4-benzylthio-3-oxazolin-5-ones leads to arylthio- and benzylthio-substituted nitrile ylides, which undergo 1,3-dipolar cycloadditions with reactive dipolarophiles to give 5-membered aza-heterocycles (Schemes 1 and 2).
Peter Wipf, Heinz Heimgartner
doaj   +1 more source

Reaction profiles for quantum chemistry-computed [3 + 2] cycloaddition reactions

open access: yesScientific Data, 2023
Bio-orthogonal click chemistry based on [3 + 2] dipolar cycloadditions has had a profound impact on the field of biochemistry and significant effort has been devoted to identify promising new candidate reactions for this purpose.
Thijs Stuyver   +2 more
doaj   +1 more source

1,3-Dipolar Cycloadditions to Bicyclic Olefins. I. 1,3-Dipolar Cycloadditions to Norbornadienes [PDF]

open access: yesBulletin of the Chemical Society of Japan, 1977
Abstract The 1,3-dipolar cycloadditions of phenylglyoxylonitrile oxide, benzonitrile-N-phenylimine, or N-phenyl-C-p-nitrophenylnitrone to norbornadiene, 2,3-dicyanonorbornadiene, and 2,3-bis(methoxycarbonyl)norbornadiene give the endo-adducts, together with the exo-adducts.
Hisaji Taniguchi   +3 more
openaire   +1 more source

Copper nanoparticles on controlled pore glass (CPG) as highly efficient heterogeneous catalysts for “click reactions”

open access: yesScientific Reports, 2020
We herein report that supported copper nanoparticles (CuNPs) on commercially available controlled pore glass (CPG), which exhibit high mechanical, thermal and chemical stability as compared to other silica-based materials, serve as a useful heterogeneous
Abdolrahim A. Rafi   +2 more
doaj   +1 more source

Solvent-Free 1,3-Dipolar Cycloadditions of Nitrones for a More Sustainable Synthesis of Glycomimetics

open access: yesReactions
1,3-Dipolar cycloadditions on nitrone dipoles are key reactions to access five-membered heterocycles, which are useful intermediates in the synthesis of biologically relevant glycomimetics.
Debora Pratesi   +4 more
doaj   +1 more source

Intramolecular 1,3-Dipolar Cycloadditions of Norbornadiene-Tethered Nitrones

open access: yes, 2016
Efficient routes to the synthesis of norbornadiene-tethered nitrones have been developed, and their intramolecular 1,3-dipolar cycloadditions were studied.
Geoffrey K. Tranmer (2520547)   +1 more
core   +2 more sources

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