Results 171 to 180 of about 8,435 (234)
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Two Organic Diselenides: Dimesityl Diselenide and Bis(2,4,6-triisopropylphenyl) Diselenide
Acta Crystallographica Section C Crystal Structure Communications, 1998The organic diselenides dimesityl diselenide [C 18 H 22 -Se 2 , (I)] and bis(2,4,6-triisopropylphenyl) diselenide [C 30 H 46 Se 2 , (II)] display normal diselenide geometries: Se-Se bond lengths are 2.3341(6) in (I) and 2.3389 (6) A in (II), and the absolute C-Se-Se-C torsion angles are 83.96 (12) in (I) and 73.38 (16)° in (II).
J. Jeske +3 more
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Chemische Berichte, 1952
AbstractEs wird die Darstellung von 21 Vertretern der bisher unbekannten Klasse unsymmetrischer Diselenide beschrieben. Ihr thermisches Verhalten sowie das Verhalten bei Oxydation und alkalischer Hydrolyse werden untersucht.
Heinrich Rheinboldt, Ernesto Giesbrecht
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AbstractEs wird die Darstellung von 21 Vertretern der bisher unbekannten Klasse unsymmetrischer Diselenide beschrieben. Ihr thermisches Verhalten sowie das Verhalten bei Oxydation und alkalischer Hydrolyse werden untersucht.
Heinrich Rheinboldt, Ernesto Giesbrecht
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Chemoselective Reduction of Organoselenocyanates to Diselenides
Tetrahedron Letters, 1997Selenocyanates possess an extremely high propensity to produce diselenides on reaction with selenols or selenolates. This is effectively observed when one molar equivalent of metal hydride or lithium triethyl borohydride or one fourth molar equivalent of metal borohydrides are reacted with organic selenocyanates.
Krief, A., Delmotte, C., Dumont, W.
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A Convenient Synthesis of 4,4′-Dimethylaminodiphenyl Diselenide and 4,4′-Dinitrodiphenyl Diselenide
Synthetic Communications, 1986Abstract A simple, rapid and efficient synthesis of 4,4′-dimethylamino-diphenyl diselenide 1 and 4,4′-dinitrodiphenyl diselenide 2 is described. The method consists of the reductive cleavage of the Se-CN linkage in the corresponding aryl selenocyanates by sodium borohydride followed by air oxidation of the resulting seleno-lates.
B. Mario Pinto +2 more
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Study of Grains and Boundaries of Molybdenum Diselenide and Tungsten Diselenide Using Liquid Crystal
Nano Letters, 2017Direct observation of grains and boundaries is a vital factor in altering the electrical and optoelectronic properties of transition metal dichalcogenides (TMDs), that is, MoSe2 and WSe2. Here, we report visualization of grains and boundaries of chemical vapor deposition grown MoSe2 and WSe2 on silicon, using optical birefringence of two-dimensional ...
Muhammad Arslan Shehzad +6 more
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Tetrahedron, 2021
Abstract A novel reaction condition has been developed for the synthesis of unsymmetrical glycosyl diselenide derivatives in excellent yield by the reaction of glycosyl selenocyanates as selenol surrogates with symmetrical diselenides in the presence of hydrazine monohydrate at room temperature.
Tapasi Manna +2 more
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Abstract A novel reaction condition has been developed for the synthesis of unsymmetrical glycosyl diselenide derivatives in excellent yield by the reaction of glycosyl selenocyanates as selenol surrogates with symmetrical diselenides in the presence of hydrazine monohydrate at room temperature.
Tapasi Manna +2 more
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2,2′-Dipyridyl diselenide is a better antioxidant than other disubstituted diaryl diselenides
Molecular and Cellular Biochemistry, 2012The aim of this study was to investigate the in vitro antioxidant activity of 2,2'-dipyridyl diselenide (e) by comparing this effect with m-trifluoromethyl-diphenyl diselenide (a), p-fluor-diphenyl diselenide (b), p-chloro-diphenyl diselenide (c), and p-methoxyl-diphenyl diselenide (d) in rat liver homogenate.
Cristiane, Luchese +3 more
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Lithium diselenide in aprotic medium - a convenient reagent for synthesis of organic diselenides
Tetrahedron, 1988Abstract The reduction of selenium with lithium in THF in the presence of diphenylacetylene as a catalyst afforded lithium diselenide, which reacted with electrophiles giving alkyl or aryl diselenides 1 - 3 and selenides 4 , as by-products. The useful method for preparation of diselenides based on this reaction was elaborated.
Ludwik Syper, Jacek Mlochowski
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Azomethine diselenides: Supramolecular structures and facile formation of a bis-oxazoline diselenide
Journal of Organometallic Chemistry, 2012Abstract A series of N2Se2 and N2Se2O2 acyclic Schiff base diselenides ( 3 – 9 ) have been synthesized by condensation of bis( o -formylphenyl) diselenide and amines (aniline, p -bromoaniline, benzylamine, ethanolamine, 1-aminopropanol, 2-aminophenol).
Snigdha Panda +4 more
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On the polymorphism of niobium diselenide
Journal of the Less Common Metals, 1971Abstract Four polymorphe of niobium diselenide have been found, viz. , 1 s -NbSe 2 , stable above 980 °C, 4 s (d)-NbSe 2 , stable between 980° and 910 °C, and the 2 s (a)- and 4 s (a)-forms stable at lower temperatures; 4 s (a)-NbSe 2 is somewhat richer in selenium than the 2 s (a)-form.
F. Kadijk, F. Jellinek
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