Results 41 to 50 of about 1,879 (233)

Crystal structures of ethyl (2S*,2′R*)-1′-methyl-2′′,3-dioxo-2,3-dihydrodispiro[1-benzothiophene-2,3′-pyrrolidine-2′,3′′-indoline]-4′-carboxylate and ethyl (2S*,2′R*)-5′′-chloro-1′-methyl-2′′,3-dioxo-2,3-dihydrodispiro[1-benzothiophene-2,3′-pyrrolidine-2′,3′′-indoline]-4′-carboxylate

open access: yesActa Crystallographica Section E, 2014
In the title compounds, C22H20N2O4S, (I), and C22H19ClN2O4S, (II), the pyrrolidine rings have twist conformations on the spiro–spiro C—C bonds. In (I), the five-membered ring of the oxindole moiety has an envelope conformation with the spiro C atom as ...
M. P. Savithri   +5 more
doaj   +1 more source

Crystal structure of ethyl 1′,5-dimethyl-2′′,3-dioxo-3H-dispiro[benzo[b]thiophene-2,3′-pyrrolidine-2′,3′′-indoline]-4′-carboxylate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compound, C23H22N2O4S, crystallized with two independent molecules (A and B) in the asymmetric unit. They have very similar conformations with the pyrrolidine ring having a twisted conformation, on the Cspiro—Cspiro bond, in both molecules.
R. Raja   +4 more
doaj   +1 more source

Phosphorus-nitrogen compounds: Part 69—Unsymmetrical dispiro(N/N)cyclotriphosphazenes containing different pendant arms: syntheses, characterization, stereogenism, photophysical and bioactivity studies

open access: yesResearch on chemical intermediates (Print), 2023
In this research, the starting compounds tetrachloromonospirocyclotriphosphazenes, (BzSpiro-5)R^1(N_3P_3)Cl_4 [Bz: Benzyl; R^1: Me ( 1 ) and R^1: Et ( 2 )], were synthesized from the reactions of hexachlorocyclotriphosphazene, N_3P_3Cl_6 ( HCCP , trimer)
Reşit Cemaloğlu   +7 more
semanticscholar   +1 more source

The Diarylprolinol Silyl Ethers: After 20 Years Still Opening New Doors in Asymmetric Catalysis

open access: yesAngewandte Chemie, Volume 138, Issue 11, 9 March 2026.
Catalysis Rules! The year 2025 marks the 20th anniversary of diarylprolinol silyl ethers in asymmetric organocatalysis. During the first decade after their discovery, these catalysts have been established as one of the most versatile tools in aminocatalysis. Although now considered mature, recent years have witnessed renewed innovation.
Enrico Marcantonio   +2 more
wiley   +2 more sources

Langgestreckte Moleküle von Dispiro[5.1.5.2]‐Typ

open access: yesChemische Berichte, 1992
Rod‐Like Dispiro[5.1.5.2] CompoundsA number of symmetrically and unsymmetrically substituted spiro compounds were synthesized starting from the dispiro[5.1.5.2]trione 1. The trans‐trans isomers of 2, 3, 6–10, and 11 were separated from the cis‐cis and cis‐trans isomers.
Vögtle, F., Hartmann, R., Boettcher, J.
openaire   +2 more sources

Dispiro[fluorene-9,5′-[1,2,3,4]tetrathiane-6′,9′′-fluorene] [PDF]

open access: yesActa Crystallographica Section C Crystal Structure Communications, 2001
The tetrathiane ring of the title compound, C26H16S4, has a chair conformation and the molecule has approximate C2 symmetry. Each of the two fluorene ring systems is virtually planar, with the ring planes intersecting at an angle of 67.58 (5)°. This novel compound has been formed as a side product from the treatment of 9H-fluorene-9-thione with methyl ...
Linden, Anthony   +2 more
openaire   +4 more sources

Development of spiro-3-indolin-2-one containing compounds of antiproliferative and anti-SARS-CoV-2 properties

open access: yesScientific Reports, 2022
A series of 1″-(alkylsulfonyl)-dispiro[indoline-3,2′-pyrrolidine-3′,3″-piperidine]-2,4″-diones 6a‒o has been synthesized through regioselective multi-component azomethine dipolar cycloaddition reaction of 1-(alkylsulfonyl)-3,5-bis(ylidene)-piperidin-4 ...
Nehmedo G. Fawazy   +13 more
doaj   +1 more source

Dispiro-1,2,4,5-tetraoxanes via Ozonolysis of Cycloalkanone O-Methyl Oximes:  A Comparison with the Peroxidation of Cycloalkanones in Acetonitrile−Sulfuric Acid Media

open access: yes, 2016
Dispiro-1,2,4,5-tetraoxanes via Ozonolysis of Cycloalkanone O-Methyl Oximes:  A Comparison with the Peroxidation of Cycloalkanones in Acetonitrile−Sulfuric Acid ...
Yuxiang Dong (1377870)   +1 more
core   +1 more source

An effective one-pot access to polynuclear dispiroheterocyclic structures comprising pyrrolidinyloxindole and imidazothiazolotriazine moieties via a 1,3-dipolar cycloaddition strategy

open access: yesBeilstein Journal of Organic Chemistry, 2016
An effective and highly regio- and diastereoselective one-pot method for the synthesis of new polynuclear dispiroheterocyclic systems with five stereogenic centers (dispiro[imidazo[4,5-e]thiazolo[3,2-b]-1,2,4-triazine-6,3′-pyrrolidine-2′,3′′-indoles ...
Alexei N. Izmest’ev   +9 more
doaj   +1 more source

Synthesis of 1-azaspiro[4.4]nonan-1-oxyls via intramolecular 1,3-dipolar cycloaddition

open access: yesBeilstein Journal of Organic Chemistry, 2019
Sterically shielded nitroxides of the pyrrolidine series have shown the highest resistance to reduction. Here we report the synthesis of new pyrrolidine nitroxides from 5,5-dialkyl-1-pyrroline N-oxides via the introduction of a pent-4-enyl group to the ...
Yulia V. Khoroshunova   +5 more
doaj   +1 more source

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