Results 71 to 80 of about 1,947 (193)

Crystal structure and molecular Hirshfeld surface analysis of acenaphthene derivatives obeying the chlorine–methyl exchange rule

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
Instances of crystal structures that remain isomorphous in spite of some minor changes in their respective molecules, such as change in a substituent atom/group, can provide insights into the factors that govern crystal packing.
R. Sribala   +3 more
doaj   +1 more source

Antitumor Activity of Artemisinin and Its Derivatives: From a Well-Known Antimalarial Agent to a Potential Anticancer Drug [PDF]

open access: yes, 2011
Improvement of quality of life and survival of cancer patients will be greatly enhanced by the development of highly effective drugs to selectively kill malignant cells.
P. Crespo-Ortiz, Maria, Wei, Ming
core   +2 more sources

Heavier Diferrocenylpnictogenium Ions

open access: yesChemistry – A European Journal, Volume 31, Issue 1, January 2, 2025.
Four shades of pastel: The synthesis, reactivity and in‐depth characterisation of cationic group 15 carbene analogues is reported. Abstract The synthesis, characterization and reactivity of the diferrocenylphosphenium ion [Fc2P]+ was extended to the heavier diferrocenylpnictogenium ions, [Fc2E]+ (E=As, Sb, Bi).
Corina Stoian   +6 more
wiley   +1 more source

Adventures in the Chemistry of Multicomponent and Domino Reactions

open access: yesEuropean Journal of Organic Chemistry, Volume 27, Issue 24, June 24, 2024.
The present article presents a personalized review of multicomponent and domino reactions directed towards the synthesis of complex heterocyclic products. Chemistry includes the combination of Knoevenagel with hetero‐Diels‐Alder reactions, [3+2] cycloadditions and enamine cyclizations.
Peter Langer
wiley   +1 more source

A Diastereoselective Synthesis of Dispiro[oxindole-cyclohexanone]pyrrolidines by 1,3-Dipolar Cycloaddition

open access: yesMolecules, 2017
For the first time, arylmethylidene cyclohexanones that are non-symmetrical due to the presence of peripheral substituents were studied in 1,3-dipolar cycloaddition reactions.
Alexander Anis’kov   +3 more
doaj   +1 more source

Selective synthesis of iminodioxaspirononanes and diazaspirononanes using formic acid-activated Mn(III) oxidation of N1,N3-disubstitued malonamides with 1,1-diarylethenes [PDF]

open access: yes, 2022
The Mn(III)-based oxidation of N1,N3-disubstituted malonamides with alkenes by Kurosawa spirolactonization using malonic acid afforded iminodihydrofurans.
Hiroshi, Nishino   +4 more
core  

Hydrindacene‐Based Zinc Aryl Thiolate and Aryl Selenolate Zn(EMSFluind)2 (E=S, Se)

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 650, Issue 9-10, May 17, 2024.
The bulky s‐hydrindacene‐based MSFluind substituent was used to generate thiol 1S and selenol 1Se and the corresponding zinc aryl thiolate 2S and selenolate 2Se, all of which were structurally characterized using single crystal XRD. Abstract The bulky aryl thiol, MSFluindSH (1S), and aryl selenol, MSFluindSeH (1Se), possessing a tetramethyl‐s ...
Pascal Komorr   +2 more
wiley   +1 more source

Crystal structure of 2'H,7'H-dispiro[fluorene-9,2'-dibenzo[c,e]- oxepine-7',9"-fluorene], C38H24O

open access: yesZeitschrift für Kristallographie - New Crystal Structures, 2003
C38H24O, monoclinic, P121/n1 (No. 14), a = 10.737(2) Å, b = 16.963(3) Å, c = 15.246(3) Å, β = 109.30(3)°, V = 2620.8 Å3, Z = 4, Rgt(F) = 0.088, wRref(F2) = 0.252, T = 293 K.
Ibragimov B. T.   +3 more
doaj   +2 more sources

Synthesis of 5α-Androstane-17-spiro-δ-lactones with a 3-Keto, 3-Hydroxy, 3-Spirocarbamate or 3-Spiromorpholinone as Inhibitors of 17β-Hydroxysteroid Dehydrogenases

open access: yesMolecules, 2013
We synthesized two series of androstane derivatives as inhibitors of type 3 and type 5 17β-hydroxysteroid dehydrogenases (17β-HSDs). In the first series, four monospiro derivatives at position C17 were prepared from androsterone (ADT ...
Donald Poirier   +3 more
doaj   +1 more source

A novel route for the synthesis of six- and seven-membered 6-trimethylsilylspiro4,nalk-6-enes [PDF]

open access: yes, 2012
A novel route for the synthesis of 6-trimethylsilylspiro4,5dec-6-ene and 6-trimethylsilylspiro4,6undec-6-ene by the Wurtz-Fittig type coupling reaction of 6-iodospiro4,5dec-6-ene and 6-iodospiro4,6undec-6-ene with alkali metals and chlorotrimethylsilane ...
Hari Prasad, S., Venkatesha, M.A.
core  

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