Results 91 to 100 of about 1,566,044 (372)

De Svante Arrhenius ao peagâmetro digital: 100 anos de medida de acidez From Svante Arrhenius to the digital ph meter: a century of acidity measurement

open access: yesQuímica Nova, 2007
This work describes the establishment of the concept of pH and the evolution of its measurement. The origin of the pH definition can be found in the development of the chemistry of aqueous solutions during the XIXth century. The electrolytic dissociation
Michelle da Silva Gama   +1 more
doaj   +1 more source

Rovibrational Internal Energy Transfer and Dissociation of High-Temperature Oxygen Mixture [PDF]

open access: yesarXiv, 2022
This work constructs a rovibrational state-to-state model for the $\text{O}_2$+$\text{O}_2$ system leveraging high-fidelity potential energy surfaces and quasi-classical trajectory calculations. The model is used to investigate internal energy transfer and non-equilibrium reactive processes in dissociating environment using a master equation approach ...
arxiv  

The accumulation of myeloid‐derived suppressor cells participates in abdominal infection‐induced tumor progression through the PD‐L1/PD‐1 axis

open access: yesMolecular Oncology, EarlyView.
This study explores how sepsis affects GC progression by creating an immunosuppressive environment. Our findings reveal that sepsis promotes immune dysregulation, enhancing tumor growth and metastasis. Targeting the PD‐1/PD‐L1 pathway with monoclonal antibodies shows potential for restoring immune function and improving outcomes in cancer patients ...
Yiding Wang   +10 more
wiley   +1 more source

Eigenstates of Thiophosgene Near the Dissociation Threshold -- Deviations From Ergodicity [PDF]

open access: yes, 2013
A subset of the highly excited eigenstates of thiophosgene (SCCl$_{2}$) near the dissociation threshold are analyzed using sensitive measures of quantum ergodicity. We find several localized eigenstates, suggesting that the intramolecular vibrational energy flow dynamics is nonstatistical even at such high levels of excitations.
arxiv   +1 more source

Excited states of Pt(PF₃)₄ andb their role in focused electron beam nanofabrication [PDF]

open access: yes, 2016
Electron induced chemistry of metal-containing precursor molecules is central in focused electron beam induced deposition (FEBID). While some elementary processes leading to precursor decomposition were quantitatively characterized, data for neutral ...
Allan, Michael   +2 more
core  

Plasma‐activated media selectively induces apoptotic death via an orchestrated oxidative stress pathway in high‐grade serous ovarian cancer cells

open access: yesMolecular Oncology, EarlyView.
High‐grade serous ovarian cancer (HGSOC) is the most common and aggressive type of ovarian cancer with urgent need for new treatment strategies. This study evaluates plasma‐activated media (PAM) as a novel treatment for HGSOC, showing its ability to selectively induce oxidative stress and apoptosis in HGSOC cell lines, patient ascites cells and primary
Lorena T. Davies   +9 more
wiley   +1 more source

Real-Space In Situ Bond Energies: Toward A Consistent Energetic Definition of Bond Strength [PDF]

open access: yes, 2018
CTQ2015-65790-P; GRUPIN14-049, FICYT, Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la ...
Costales Castro, María Aurora   +3 more
core   +2 more sources

TRPM4 contributes to cell death in prostate cancer tumor spheroids, and to extravasation and metastasis in a zebrafish xenograft model system

open access: yesMolecular Oncology, EarlyView.
Transient receptor potential melastatin‐4 (TRPM4) is overexpressed in prostate cancer (PCa). Knockout of TRPM4 resulted in reduced PCa tumor spheroid size and decreased PCa tumor spheroid outgrowth. In addition, lack of TRPM4 increased cell death in PCa tumor spheroids.
Florian Bochen   +6 more
wiley   +1 more source

Dissociation of the benzene molecule by UV and soft X-rays in circumstellar environment [PDF]

open access: yes, 2008
Benzene molecules, present in the proto-planetary nebula CRL 618, are ionized and dissociated by UV and X-ray photons originated from the hot central star and by its fast wind. Ionic species and free radicals produced by these processes can lead to the formation of new organic molecules.
arxiv   +1 more source

Solving the CH$_4^-$ riddle: the fundamental role of spin to explain metastable anionic methane

open access: yes, 2019
When atoms or molecules exist in the form of stable negative ions, they play a crucial role in the gas phase chemistry. Determining the existence of such an ion, its internal energy and its stability are necessary prerequisites to analyze the role of ...
Hinojosa, Guillermo   +3 more
core   +1 more source

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