Bond and Antibond Resonances: A Unified Framework for Singlet Biradical Character
The electronic structure of a variety of singlet biradicaloids may be described in the Lewis picture using single antibonds as the central bonding motif. In conjunction with a consistent set of biradical indicators, we can resolve some long‐standing disputes over the biradical character of molecules such as O3 and S2N2.
Daniel T. Gschwind, Jonas Bresien
wiley +1 more source
Perching of quadrotor using adaptive second-order continuous control in the presence of uncertainties. [PDF]
Gupta S +4 more
europepmc +1 more source
Open halogen‐bonded networks have been prepared from building blocks that incorporate both iodoalkyne halogen bond donors and a pyridine‐N‐oxide halogen bond acceptor. An initially‐formed 3D network containing dioxane in its channels undergoes an unprecedented transition to a 2D material when crystals are exposed to diethyl ether.
Jordan N. Smith +4 more
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Collaborative Control for a Robot Manipulator via Interaction-Force-Based Impedance Method and Extremum Seeking Optimization. [PDF]
Pi M.
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A hidden Markov model and reinforcement learning‐based strategy for fault‐tolerant control
Abstract This study introduces a data‐driven control strategy integrating hidden Markov models (HMM) and reinforcement learning (RL) to achieve resilient, fault‐tolerant operation against persistent disturbances in nonlinear chemical processes. Called hidden Markov model and reinforcement learning (HMMRL), this strategy is evaluated in two case studies
Tamera Leitao +2 more
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Advanced mathematical modeling and simulation of high altitude balloons for precision stratospheric data collection. [PDF]
Slimene MB, Khlifi MA, Tlili I.
europepmc +1 more source
The rock failure mode is significantly influenced by the contributing factors, such as the joint inclination, the initial confining pressure, and the unloading point. We found six typical rock failure modes after a large number of numerical tests. Abstract Excavation unloading damages rock masses, with preferential failure along geological defects in ...
Fei Liu +4 more
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Nonlinear control of quadrotor UAV under rotor failure for robust trajectory tracking. [PDF]
Simha A, Ambroziak L.
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This paper investigates the high‐pressure water jet‐pick combined rock‐breaking mode (HPC), which employs high‐pressure water jets to precut grooves on both sides of the picks. The rock‐breaking patterns and performance of the HPC method are obtained, and the auxiliary rock‐breaking mechanism of water jet grooving is revealed.
Jingjing Lu +6 more
wiley +1 more source
Data-Driven Parameter Identification of Synchronous Generators: A Three-Stage Framework with State Consistency and Grid Decoupling. [PDF]
Peykarporsan R +3 more
europepmc +1 more source

