Results 1 to 10 of about 5,307,006 (250)

Reverse dynamic nuclear polarisation for indirect detection of nuclear spins close to unpaired electrons [PDF]

open access: yesMagnetic Resonance, 2022
Polarisation transfer schemes and indirect detection are central to magnetic resonance. Using the trityl radical OX063 and a pulse electron paramagnetic resonance spectrometer operating in the Q-band (35 GHz, 1.2 T), we show here that it is possible to ...
N. Wili   +2 more
doaj   +1 more source

A primer in pulse EPR-based hyperfine spectroscopy for NMR spectroscopists

open access: yesJournal of Magnetic Resonance Open, 2023
The theoretical foundations of NMR and EPR are very similar. Nevertheless, the fields differ significantly in practical aspects. This primer is an attempt to bridge some of the gaps between the fields, and at the same time it highlights some applications
Nino Wili
doaj   +1 more source

Electron-nuclear double resonance [PDF]

open access: yesPhotosynthesis Research, 2009
The application of electron-nuclear double resonance (ENDOR) spectroscopy for the investigation of photosynthetic systems is reviewed. The basic principles of continuous wave and pulse ENDOR are presented. Selected examples of the application of the ENDOR technique for studying stable and transient paramagnetic species, including cofactor radical ions,
Kulik, Leonid, Lubitz, Wolfgang
openaire   +2 more sources

High-Field (3.4 T) Electron Paramagnetic Resonance, 1H Electron-Nuclear Double Resonance, ESEEM, HYSCORE, and Relaxation Studies of Asphaltene Solubility Fractions of Bitumen for Structural Characterization of Intrinsic Carbon-Centered Radicals

open access: yesNanomaterials, 2022
Petroleum asphaltenes are considered the most irritating components of various oil systems, complicating the extraction, transportation, and processing of hydrocarbons. Despite the fact that the paramagnetic properties of asphaltenes and their aggregates
Marat Gafurov   +4 more
doaj   +1 more source

Radiation-Induced Stable Radicals in Calcium Phosphates: Results of Multifrequency EPR, EDNMR, ESEEM, and ENDOR Studies

open access: yesApplied Sciences, 2021
This article presents the results of a study of radiation-induced defects in various synthetic calcium phosphate (CP) powder materials (hydroxyapatite—HA and octacalcium phosphate—OCP) by electron paramagnetic resonance (EPR) spectroscopy at the X, Q ...
Fadis F. Murzakhanov   +10 more
doaj   +1 more source

Electron-nuclear double resonance of interstitial chromium in silicon [PDF]

open access: yesPhysical Review B, 1987
The positively charged state of interstitial chromium in silicon was investigated using electron-nuclear double resonance. We have found the hyperfine interaction of the impurity electrons with nine shells of surrounding silicon neighbors containing 102 atoms.
van Kemp, R.   +2 more
openaire   +3 more sources

Pulsed Electron‐Nuclear Double Resonance in the Fourier Regime

open access: yesChemPhysChem, 2022
Abstract Nuclear magnetic resonance (NMR) spectroscopy provides atomic‐level molecular structural information. However, in molecules containing unpaired electron spins, NMR signals are difficult to measure directly. In such cases, data is obtained using the electron‐nuclear double resonance (ENDOR) method, where nuclei are detected ...
Nir Dayan   +4 more
openaire   +2 more sources

Syntheses and Electrochemical and EPR Studies of Porphyrins Functionalized with Bulky Aromatic Amine Donors

open access: yesMolecules, 2023
A series of nickel(II) porphyrins bearing one or two bulky nitrogen donors at the meso positions were prepared by using Ullmann methodology or more classical Buchwald–Hartwig amination reactions to create the new C-N bonds.
Mary-Ambre Carvalho   +10 more
doaj   +1 more source

High-resolution nanoscale NMR for arbitrary magnetic fields

open access: yesCommunications Physics, 2023
Nitrogen vacancy (NV) centers are a major platform for the detection of nuclear magnetic resonance (NMR) signals at the nanoscale. To overcome the intrinsic electron spin lifetime limit in spectral resolution, a heterodyne detection approach is widely ...
Jonas Meinel   +8 more
doaj   +1 more source

Structures of Impurity Defects in Lithium Niobate and Tantalate Derived from Electron Paramagnetic and Electron Nuclear Double Resonance Data

open access: yesCrystals, 2021
Point intrinsic and extrinsic defects, especially paramagnetic ions of transition metals and rare-earth elements, have essential influence on properties of lithium niobate, LN and tantalate, LT, and often determine their suitability for numerous ...
Valentin G. Grachev   +1 more
doaj   +1 more source

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