Cross‐Polarization Electron‐Nuclear Double Resonance Spectroscopy [PDF]
AbstractMagnetic nuclei in the proximity of a paramagnetic center can be polarized through electron‐nuclear cross‐polarization and detected in electron‐nuclear double resonance (ENDOR) spectroscopy. This principle is demonstrated in a single‐crystal model sample as well as on a protein, the β2 subunit of E.coli ribonucleotide reductase (RNR), which ...
Rizzato, Roberto, Bennati, Marina
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Nuclear magnetic resonance [PDF]
Podeu consultar el llibre complet a: http://hdl.handle.net/2445/32166This article reviews the principles and methods of nuclear magnetic resonance spectroscopy, and gives examples of applications carried out at our Facility, which illustrate the ...
Molins i Montserrat, Mª Antònia +4 more
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A series of nickel(II) porphyrins bearing one or two bulky nitrogen donors at the meso positions were prepared by using Ullmann methodology or more classical Buchwald–Hartwig amination reactions to create the new C-N bonds.
Mary-Ambre Carvalho +10 more
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High-resolution nanoscale NMR for arbitrary magnetic fields
Nitrogen vacancy (NV) centers are a major platform for the detection of nuclear magnetic resonance (NMR) signals at the nanoscale. To overcome the intrinsic electron spin lifetime limit in spectral resolution, a heterodyne detection approach is widely ...
Jonas Meinel +8 more
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Extending the range of distances accessible by 19F electron-nuclear double resonance in proteins using high-spin Gd(III) labels [PDF]
Fluorine electron-nuclear double resonance (19F ENDOR) has recently emerged as a valuable tool in structural biology for distance determination between F atoms and a paramagnetic center, either intrinsic or conjugated to a biomolecule via spin labeling ...
Alexey, Bogdanov +7 more
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Strategies for synthesis of yardsticks and abaci for nanometre distance measurements by pulsed EPR [PDF]
Silvia Valera is grateful for support by EPSRC and Bela E. Bode acknowledges support by EastCHEM.Pulsed electron paramagnetic resonance (EPR) techniques have been found to be an efficient tool for elucidation of structure in complex biological systems as
Bode, Bela Ernest +4 more
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Site-selective generation of lanthanoid binding sites on proteins using 4-fluoro-2,6-dicyanopyridine [PDF]
The paramagnetism of a lanthanoid tag site-specifically installed on a protein provides a rich source of structural information accessible by nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) spectroscopy.
S. Mekkattu Tharayil +10 more
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Electron-nuclear-double-resonance studies of spinach plastocyanin [PDF]
Electron-nuclear-double-resonance (ENDOR) studies of spinach plastocyanin revealed that 14N-hyperfine couplings from its two co-ordinated imidazole groups are characteristically small in anisotropy and relatively high in ENDOR frequencies and that the two imidazole groups are magnetically equivalent.
H, Yokoi, Y, Ohba, T, Takabe
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Coherent state transfer between an electron and nuclear spin in (15)N@C(60). [PDF]
Electron spin qubits in molecular systems offer high reproducibility and the ability to self-assemble into larger architectures. However, interactions between neighboring qubits are "always on," and although the electron spin coherence times can be ...
G. Andrew D. Briggs +29 more
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Low temperature transport and evidence for nuclear order in GaAs Quantum Wires [PDF]
In this thesis we focus on low temperature transport through cleaved edge overgrowth (CEO) quantum wires. This thesis is motivated by recent theoretical work on one hand that predicts the formation of a nuclear helimagnet in presence of a Luttinger ...
Scheller, Christian Philipp
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