Results 261 to 270 of about 43,957 (340)

Flow-Enabled, Modular Access to α,α-Difluoromethylene Amines. [PDF]

open access: yesAngew Chem Int Ed Engl
Nagornîi D   +5 more
europepmc   +1 more source

Fluoride-Transfer Asymmetric Allylic Alkylation Enables Regiodivergent, Stereoselective Cross-Electrophile Coupling. [PDF]

open access: yesAngew Chem Int Ed Engl
Duran J   +5 more
europepmc   +1 more source

The Carnosine-HNE Michael Adduct as a Redox-Active Species Associated with Nrf2-Dependent Antioxidant and Anti-Inflammatory Responses. [PDF]

open access: yesAntioxidants (Basel)
Altomare A   +17 more
europepmc   +1 more source

Asymmetric Reduction of Unactivated Alkenes

open access: yesChemistry – A European Journal, Volume 32, Issue 18, 14 May 2026.
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner   +3 more
wiley   +1 more source

Nickel‐Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3‐Substituted Pyrrolidines

open access: yesAngewandte Chemie, Volume 138, Issue 20, 11 May 2026.
Metal‐catalyzed enantioconvergent substitutions of unactivated cyclic electrophiles by organometallic nucleophiles have not previously been reported. Herein, a chiral nickel catalyst is described that achieves this objective, coupling 3‐iodopyrrolidine derivatives with arylzinc nucleophiles.
Ting Hei Matthew Wong   +2 more
wiley   +2 more sources

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